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What is the difference in oxidation stat...

What is the difference in oxidation state of nitrogen in between hydroxyl amine `(NH_(2)OH)` and hydrazine `(N_(2)H_(4))` ?

A

`+5`

B

`+3`

C

`-3`

D

1

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AI Generated Solution

The correct Answer is:
To find the difference in oxidation state of nitrogen in hydroxylamine (NH₂OH) and hydrazine (N₂H₄), we can follow these steps: ### Step 1: Determine the oxidation state of nitrogen in hydroxylamine (NH₂OH) 1. **Assign variables**: Let the oxidation state of nitrogen be \( x \). 2. **Count contributions from hydrogen and hydroxyl group**: - There are 2 hydrogen atoms, each contributing \( +1 \) (total \( +2 \)). - The hydroxyl group (OH) contributes \( -1 \). 3. **Set up the equation**: The sum of oxidation states must equal zero (since the molecule is neutral): \[ x + 2 - 1 = 0 \] 4. **Solve for \( x \)**: \[ x + 1 = 0 \implies x = -1 \] Therefore, the oxidation state of nitrogen in hydroxylamine is \( -1 \). ### Step 2: Determine the oxidation state of nitrogen in hydrazine (N₂H₄) 1. **Assign variables**: Let the oxidation state of each nitrogen atom be \( x \). Since there are 2 nitrogen atoms, we have \( 2x \). 2. **Count contributions from hydrogen**: - There are 4 hydrogen atoms, each contributing \( +1 \) (total \( +4 \)). 3. **Set up the equation**: The sum of oxidation states must equal zero: \[ 2x + 4 = 0 \] 4. **Solve for \( x \)**: \[ 2x = -4 \implies x = -2 \] Therefore, the oxidation state of nitrogen in hydrazine is \( -2 \). ### Step 3: Calculate the difference in oxidation states 1. **Find the difference**: \[ \text{Difference} = \text{Oxidation state in hydrazine} - \text{Oxidation state in hydroxylamine} \] \[ = (-2) - (-1) = -2 + 1 = -1 \] ### Conclusion The difference in oxidation state of nitrogen between hydroxylamine and hydrazine is \( -1 \). ### Final Answer The difference in oxidation state of nitrogen in hydroxylamine (NH₂OH) and hydrazine (N₂H₄) is \( +1 \) (as the question asks for the absolute difference). ---
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AAKASH INSTITUTE ENGLISH-REDOX REACTIONS-Assignment (Section B) (Objective type Questions (one option is correct))
  1. Calculate the oxidation numbers of Cr in K(3)CrO(8):

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  2. Peroxides are basic in nature and they form hydrogen peroxides on trea...

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  3. What is the difference in oxidation state of nitrogen in between hydro...

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  4. In which one of the following changes there are transfer of five elect...

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  5. How many gm of K(2)Cr(2)O(7) is present in 1 L of its N/10 solution in...

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  6. When Cu(2)S is converted into Cu^(2+) & SO(2) then equivalent weight o...

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  7. Which of the following changes involve reduction ?

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  8. FeS to Fe^(3+) + SO(3) Eq. wt. of FeS for this change is (mol. Wt....

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  9. The reaction Cl(2) + S(2)O(3)^(2-) + OH^(-) to SO(4)^(2-) + Cl^(-)...

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  10. The number of moles of KMnO4 that are needed to react completely with ...

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  11. 200 ml of 0.01 M KMnO(4) oxidise 20 ml of H(2)O(2) sample in acidic me...

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  12. If equal volumes of 1 M KMnO(4) and 1M K(2)Cr(2)O(7) solutions are all...

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  13. 4 mole of a mixture of Mohr's salt and Fe(2)(SO(4))(3) requires 500mL...

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  14. What volume of 3 molar HNO(3) is needed to oxidise 8 g of Fe^(3+), HNO...

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  15. The stoichiometric coefficient of S in the following reaction H(2)...

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  16. A volume of 12.5 mL of 0.05 M SeO(2) reacts with 25 mL of 0.1 M CrSO(4...

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  17. A sample of NaHCO(3) + Na(2)CO(3) required 20 ml of HCl using phenolph...

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  18. A sample of FeSO(4) and FeC(2)O(4) is dissolved in H(2)SO(4) . The com...

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  19. The equivalent mass of MnSO4 is half of its molecular mass when it is ...

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  20. In the titration of NaHCO(3) with HCl, indicator cannot be used

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