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FeS to Fe^(3+) + SO(3) Eq. wt. of Fe...

`FeS to Fe^(3+) + SO_(3)`
Eq. wt. of FeS for this change is (mol. Wt. of FeS=M)

A

`M/1`

B

`M/5`

C

`M/7`

D

`M/9`

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The correct Answer is:
To determine the equivalent weight of FeS for the reaction \( \text{FeS} \rightarrow \text{Fe}^{3+} + \text{SO}_3 \), we will follow these steps: ### Step 1: Write the balanced equation The reaction can be represented as: \[ \text{FeS} \rightarrow \text{Fe}^{3+} + \text{SO}_3 \] ### Step 2: Determine the oxidation states - In FeS, iron (Fe) has an oxidation state of +2, and sulfur (S) has an oxidation state of -2. - In \(\text{Fe}^{3+}\), iron has an oxidation state of +3. - In \(\text{SO}_3\), sulfur has an oxidation state of +6. ### Step 3: Calculate the change in oxidation states - For sulfur: - It changes from -2 in FeS to +6 in SO3. - Change = \( +6 - (-2) = +8 \) - For iron: - It changes from +2 in FeS to +3 in Fe3+. - Change = \( +3 - (+2) = +1 \) ### Step 4: Determine the total number of electrons transferred - The total number of electrons transferred in the reaction: - Sulfur contributes 8 electrons (from -2 to +6). - Iron contributes 1 electron (from +2 to +3). Thus, the total number of electrons involved in the reaction is: \[ 8 + 1 = 9 \text{ electrons} \] ### Step 5: Calculate the equivalent weight The formula for equivalent weight is given by: \[ \text{Equivalent Weight} = \frac{\text{Molecular Weight}}{n} \] where \( n \) is the number of electrons transferred. Given that the molecular weight of FeS is \( M \), we can substitute: \[ \text{Equivalent Weight of FeS} = \frac{M}{9} \] ### Final Answer The equivalent weight of FeS for this change is: \[ \text{Equivalent Weight} = \frac{M}{9} \] ---
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