Home
Class 12
CHEMISTRY
STATEMENT-1: In the reaction : Cl(2)+ OH...

STATEMENT-1: In the reaction : `Cl_(2)+ OH^(-) to Cl^(-) + ClO_(4)^(-)` chlorine is oxidised only
STATEMENT-2: Oxidation and reduction cannot take place alone.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the statements provided in the question, we will break down the reaction and evaluate the oxidation states of chlorine in each species involved. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction given is: \[ \text{Cl}_2 + \text{OH}^- \rightarrow \text{Cl}^- + \text{ClO}_4^- \] 2. **Determine Oxidation States**: - In \(\text{Cl}_2\), the oxidation state of chlorine (Cl) is 0 (elemental form). - In \(\text{Cl}^-\), the oxidation state of Cl is -1. - In \(\text{ClO}_4^-\), we need to calculate the oxidation state of Cl. The overall charge is -1, and oxygen has an oxidation state of -2. Since there are four oxygens: \[ \text{Let the oxidation state of Cl be } x. \] \[ x + 4(-2) = -1 \implies x - 8 = -1 \implies x = +7. \] Thus, the oxidation states are: - Cl in \(\text{Cl}_2\): 0 - Cl in \(\text{Cl}^-\): -1 - Cl in \(\text{ClO}_4^-\): +7 3. **Identify Oxidation and Reduction**: - **Oxidation** is defined as an increase in oxidation state. Here, Cl changes from 0 in \(\text{Cl}_2\) to +7 in \(\text{ClO}_4^-\), indicating oxidation. - **Reduction** is defined as a decrease in oxidation state. Here, Cl changes from 0 in \(\text{Cl}_2\) to -1 in \(\text{Cl}^-\), indicating reduction. 4. **Evaluate Statement 1**: - The statement claims that "chlorine is oxidized only." However, since chlorine is both oxidized (to +7) and reduced (to -1) in this reaction, **Statement 1 is incorrect**. 5. **Evaluate Statement 2**: - The statement claims that "oxidation and reduction cannot take place alone." This is not true, as there are reactions where only oxidation or only reduction occurs. For example: - Oxidation: \( \text{Na} \rightarrow \text{Na}^+ + e^- \) (only oxidation). - Reduction: \( \text{Cl}_2 + 2e^- \rightarrow 2\text{Cl}^- \) (only reduction). Therefore, **Statement 2 is also incorrect**. ### Conclusion: Both statements are incorrect.
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (Section F) (Matrix-Match Type Questions)|5 Videos
  • REDOX REACTIONS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (Section G) (Interger Answer Type Questions)|8 Videos
  • REDOX REACTIONS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (Section D) (Linked Comprehension Type Questions)|12 Videos
  • PRINCIPLES OF QUALITATIVE ANALYSIS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (SECTION H)|9 Videos
  • SOLUTIONS

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGMENT (SECTION-J) AAKASH CHALLENGERS QUESTIONS|10 Videos

Similar Questions

Explore conceptually related problems

In the reaction :Cl_(2)+OH^(-)rarrCl^(-)+ClO_(4)^(-)+H_(2)O :-

In the reaction Cl_2 + OH^(-) to ClO_3^(-) + Cl^(-) + H_2O the stoichiometric coefficient of Cl_2 and Cl^- respectively are

In the reaction : MnO_(2) + 4HCI to MnCl_(2) + 2H_(2)O + Cl_(2) (a) Name the compound (i) oxidised, (ii) reduced. (b) Define oxidation and reduction on its basis of electrons. .

Hg_2Cl_2 + NH_4OH to

For the reaction : I^(-)+ClO_(3)^(-)+H_(2)SO_(4) to Cl^(-)+HSO_(4)^(-)+I_(2) The correct statement(s) in the balanced equation is/are:

What is the oxidation stae of Cl in (a) CrO_(2)Cl_(2) , (b) HClO_(4)

The order of Cl - O bond energy in ClO^(-), ClO_(2)^(-), ClO_(3)^(-), CIO_(4)^(-) is

10 g carbon reacts with 100 g Cl_(2) to form C Cl_(4) The correct statement is

The reaction 3ClO^(-)(aq)rarrClO_(3)^(-)(aq)+2Cl^(-)(aq) an example of :

A : Cl_(2) on reaction with NaOH (cold and dilute) gives NaClO_(3) . R : Cl_(2) get oxidized only in this reaction .