Home
Class 12
CHEMISTRY
IO(3)^(-)+I^(-)+H^(+) to...

`IO_(3)^(-)+I^(-)+H^(+) to`

A

5,1,6

B

1,5,6

C

6,1,5

D

5,6,1

Text Solution

AI Generated Solution

The correct Answer is:
To solve the redox reaction involving \( IO_3^- \), \( I^- \), and \( H^+ \), we will follow a systematic approach to balance the reaction and determine the coefficients of each species involved. ### Step-by-Step Solution **Step 1: Identify the oxidation states.** - For \( IO_3^- \): The oxidation state of iodine (I) can be calculated as follows: \[ x - 6 = -1 \implies x = +5 \] - For \( I^- \): The oxidation state is \( -1 \). - For \( I_2 \): The oxidation state is \( 0 \). **Step 2: Write the half-reactions.** - **Oxidation half-reaction** (for \( I^- \) to \( I_2 \)): \[ 2 I^- \rightarrow I_2 + 2 e^- \] - **Reduction half-reaction** (for \( IO_3^- \) to \( I_2 \)): \[ 2 IO_3^- + 10 e^- + 12 H^+ \rightarrow 6 I_2 + 6 H_2O \] **Step 3: Balance the half-reactions.** - The oxidation half-reaction is already balanced. - For the reduction half-reaction, we need to ensure that both iodine atoms and the charges are balanced. We have: - 2 moles of \( IO_3^- \) giving 6 moles of \( I_2 \). - The electrons and protons are balanced as well. **Step 4: Combine the half-reactions.** - To combine, we need to ensure that the electrons cancel out. We multiply the oxidation half-reaction by 5: \[ 10 I^- \rightarrow 5 I_2 + 10 e^- \] - Now, add the two half-reactions: \[ 2 IO_3^- + 10 I^- + 12 H^+ \rightarrow 6 I_2 + 6 H_2O \] **Step 5: Write the final balanced equation.** - The final balanced equation is: \[ 2 IO_3^- + 10 I^- + 12 H^+ \rightarrow 6 I_2 + 6 H_2O \] **Step 6: Determine the coefficients.** - The coefficients for the balanced equation are: - \( IO_3^- \): 2 - \( I^- \): 10 - \( H^+ \): 12 - \( I_2 \): 6 - \( H_2O \): 6 ### Final Answer The coefficients are: - \( IO_3^- \): 2 - \( I^- \): 10 - \( H^+ \): 12 - \( I_2 \): 6 - \( H_2O \): 6
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    AAKASH INSTITUTE ENGLISH|Exercise EXERCISE|20 Videos
  • REDOX REACTIONS

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT SECTION - A|35 Videos
  • REDOX REACTIONS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (Section I) (Subjective Type Questions)|38 Videos
  • PRINCIPLES OF QUALITATIVE ANALYSIS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (SECTION H)|9 Videos
  • SOLUTIONS

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGMENT (SECTION-J) AAKASH CHALLENGERS QUESTIONS|10 Videos

Similar Questions

Explore conceptually related problems

NalO_(3) reacts with NaHSO_(3) according to eaquation Io_(3)^(-)+3HSO_(3)^(-)to I^(-)+3H^(+)3SO_(4)^(2-) The weight of NaHSO_(3) required to react with 100 mL of solution containing 0.58 gm of is :

A sample of raw material contain NaNO_(3) . It contains some NaIO_(3) also. The NaIO_(3) can be used as a source of iodine, produced in the following reactions: IO_(3)^(-)+HSO_(3)^(-) to I^(-)+SO_(4)^(-) ...................(1) I^(-)+IO_(3)^(-) to I_(2)+H_(2)O ............(2) One litre of sample solution containing 396 g NaIO_(3) is treated with stoichiometric quantity of NaHSO_(3) . Now a substantial amount of solution is added to reaction mixture to bring about the reaction (2).

Oxidation number if iodine in IO_(3)^(-), IO_(4)^(-),KI and I_(2) respectively are

IO_(3)^(-) + 6OH^(-)+Cl_(2) to IO_(6)^(5-) ("periodate")+3H_2O+2Cl^(-)

I^(-) reduces IO_(3)^(-) to I_(2) and itself oxidised to I_(2) in acidic medium. Thus, final reaction is

Statement-1 : IO_(3)^(-) oxidises I^(-) to I_(2) in acidic medium. Statement-2 : HIO_(3) is formed by oxidation of I_(2) with concentrated HNO_(3) .

Hydrazine reacts with KIO_(3) in presence of HCl as : N_(2)H_(4)+IO_(3)^(-)+2H^(+)+Cl^(-) rarrICI+N_(2)+3H_(2)O The equivalent masses of N_(2)H_(4) and KIO_(3) respectively are :

Hydrazine reacts with KIO_(3) in presence of HCl as : N_(2)H_(4)+IO_(3)^(-)+2H^(+)+Cl^(-) rarrICI+N_(2)+3H_(2)O The equivalent masses of N_(2)H_(4) and KIO_(3) respectively are :

In the balanced chemical reaction IO_(3)^(ө)+aI^(ө)+bH^(ө)rarrcH_(2)O+dI_(2) a, b,c , and d , respectively, correspond to

In the balanced chemical reaction IO_(3)^(ө)+aI^(ө)+bH^(ө)rarrcH_(2)O+dI_(2) a, b,c , and d , respectively, correspond to