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Cr(OH)(3)+ClO^(-)+3OH^(-)rarr?+Cl^(-)3H(...

`Cr(OH)_(3)+ClO^(-)+3OH^(-)rarr?+Cl^(-)3H_(2)O`. The missing ion is

A

`Cr_(2)O_(7)^(2-)`

B

`Cr^(3+)`

C

`CrO_(4)^(2-)`

D

`Cr_(2)O_(3)`

Text Solution

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The correct Answer is:
To solve the question, we need to identify the missing ion in the reaction: \[ \text{Cr(OH)}_3 + \text{ClO}^- + 3\text{OH}^- \rightarrow ? + \text{Cl}^- + 3\text{H}_2\text{O} \] ### Step-by-Step Solution: 1. **Identify the Reactants:** - We have chromium hydroxide, \(\text{Cr(OH)}_3\), which contains chromium in the +3 oxidation state. - We also have hypochlorite ion, \(\text{ClO}^-\), and hydroxide ions, \(\text{OH}^-\). 2. **Determine the Products:** - The products include chloride ion, \(\text{Cl}^-\), and water, \(3\text{H}_2\text{O}\). - We need to find the missing product. 3. **Oxidation State Changes:** - In \(\text{Cr(OH)}_3\), chromium has an oxidation state of +3. - In the potential product, \(\text{CrO}_4^{2-}\) (chromate ion), chromium has an oxidation state of +6. - This indicates that chromium is being oxidized from +3 to +6. 4. **Oxidizing Agent:** - The hypochlorite ion, \(\text{ClO}^-\), acts as an oxidizing agent in this reaction, facilitating the oxidation of chromium. 5. **Balancing the Reaction:** - The hypochlorite ion oxidizes chromium hydroxide to chromate ion, \(\text{CrO}_4^{2-}\). - Therefore, the missing ion in the reaction is \(\text{CrO}_4^{2-}\). 6. **Final Reaction:** - The balanced reaction can be written as: \[ \text{Cr(OH)}_3 + \text{ClO}^- + 3\text{OH}^- \rightarrow \text{CrO}_4^{2-} + \text{Cl}^- + 3\text{H}_2\text{O} \] ### Conclusion: The missing ion in the reaction is \(\text{CrO}_4^{2-}\) (chromate ion).
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