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In a solid ,oxide (O^(2-)) ions are arr...

In a solid ,oxide `(O^(2-))` ions are arranged in ccp, cations `(A^(3+))` occupy one -sixth of tetrahedral void and cations `(B^(3+))` occupy one -third of the octahedral voids . What is the formula of the compound?

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To find the formula of the compound based on the arrangement of oxide ions and the occupation of cation voids, we can follow these steps: ### Step 1: Determine the number of oxide ions (O²⁻) in the unit cell. In a face-centered cubic (FCC) structure, the number of atoms (or ions) per unit cell is 4. Since the oxide ions are arranged in a CCP (cubic close-packed) structure, we have: - Number of O²⁻ ions = 4 ### Step 2: Calculate the number of tetrahedral voids. In an FCC structure, the number of tetrahedral voids is given by: ...
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AAKASH INSTITUTE ENGLISH-THE SOLID STATE -Assignment (SECTION - D) (ASSERTION-REASON TYPE QUESTION)
  1. In a solid ,oxide (O^(2-)) ions are arranged in ccp, cations (A^(3+)...

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  2. A : In NaCl structure, the interionic distance is a/2 (a = Unit cell e...

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  3. A : The co - ordination number of CaF(2) is 8 : 4. R : Ca^(2+) ion...

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  4. A : The number of spheres are equal to the number of octahedral voids ...

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  5. A : In Schottky defect, density of crystal decreases. R : Equal nu...

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  6. A : If a tetrad axis is passed through the unit cell of NaCl and all i...

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  7. A : A particle at the corner of CCP unit cell has (1)/(8)th of its con...

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  8. A : Glass belongs to the category of covalent network solid. R : U...

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  9. A : NaCl shows Schottky defect at room temperature. R : NaCl shows...

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  10. A : Fe(3)O(4) is ferrimagnetic at room temperature but becomes paramag...

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  11. A : In molecular solids the lattice points are occupied by the atoms o...

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  12. A : Silicon is insulator at 0 K but semiconductor at room temperature....

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  13. A : Amorphous solids are isotropic. R : Amorphous solids are not rig...

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  14. A : In NaCl coordination number of Cl^(-) ion is 6 but in CsCl coordin...

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  15. A : All crystals of same substance possess the same elements of symmet...

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  16. A : AgBr shows both Schottky and Frenkel defect. R : AgBr is a cry...

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  17. A : Number of carbon atoms per unit cell in diamond is 8. R : The ...

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  18. A : The coordination number of ionic compound depends upon radius rati...

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  19. A : Number of rectangular plane in a cubic crystal is 3. R : Recta...

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  20. A : ccp is more efficient than hcp. R : Packing fraction is differe...

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  21. A : Coordination number of both Na^(+) and Cl^(-) NaCl is 6. R : Se...

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