Home
Class 12
CHEMISTRY
If the radius of Br^(-) ion is 0.182 nn,...

If the radius of `Br^(-)` ion is 0.182 nn, how large can a cation be fit in its tetrahedral holes ?

Text Solution

AI Generated Solution

To determine how large a cation can be to fit in the tetrahedral holes formed by bromide ions (Br⁻) with a radius of 0.182 nm, we can follow these steps: ### Step 1: Understand the radius ratio for tetrahedral holes The radius ratio for a cation (R⁺) to an anion (R⁻) in a tetrahedral hole is given by the formula: \[ 0.225 < \frac{R^+}{R^-} < 0.414 \] ### Step 2: Calculate the minimum radius of the cation (R⁺) Using the lower limit of the radius ratio: ...
Promotional Banner

Topper's Solved these Questions

  • THE SOLID STATE

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT SECTION-A (OBJECTIVE)|50 Videos
  • THE SOLID STATE

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT SECTION-B (OBJECTIVE)|27 Videos
  • THE SOLID STATE

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (SECTION - D) (ASSERTION-REASON TYPE QUESTION)|20 Videos
  • THE S-BLOCK ELEMENTS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (Section-J)|10 Videos
  • THERMODYNAMICS

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (Section -D) Assertion-Reason Type Questions|15 Videos

Similar Questions

Explore conceptually related problems

If the radius of Br^(-) ion is 0.20 nn, how large can a cation be fit in its tetrahedral holes ?

If the radius of the bromide ion is 0.182 nm, how large a cation can fit in each of the tetrahedral holes ?

Br^(-) ions form close packed structure. If the radius of Br^(-) ion is 195 p, calculate the radius of the cation that just fits in the tetrahedral hole. Can a cation A^(+) having a radius of 82 pm be slipped into the octahedral hole of the crystal A^(+) Br^(-) ?

A crystalline solid AB has NaCl type structure with radius of B^(-) ion is 250 pm. Which of the following cation can be made to slip into tetrahedral site of crystals of A^(+)B^(-) ?

The radius of the bromide ion is 0.182 nm. According to the radius ratio rule the largest cation that can fit in tetrahedral hole has radius

If the radius of anion is 0.20 nm , the maximum radius of cation which can be filleed in respective voids is correctly matched in

If the radius of a Chloride ion is 0.154 nm, then what is the maximum size of a cation that can fit in each of its octahedral voids?

In the closed packing of atoms A ("radius":r_(a)) , the radius of atom B that can be fitted into tetrahedral void is:

CaS exists in a cubic close packed arrangement of S^(2-) ions in which Ca^(2+) ions occupy 1/2 of the available tetrahedral holes. How many Ca^(2+)and S^(2-) ions are contained in the unit cell?

Try to answer the following: (i) In Zinc Blende structure there is one Zn^(+2) ion per S^(2-) ion. But the radius ratio lies in the range of Tetrahedral void and there are two tetrahedral voids available per S^(2-) . Can you given the idea about the arrangement of the lattice. (ii) What is the striking difference between the Fluorite and the Anit-fluorite structures

AAKASH INSTITUTE ENGLISH-THE SOLID STATE -Try Yourself
  1. A compound formed by elements A and B crystallizes in the cubic arrang...

    Text Solution

    |

  2. The radius of the Na^(+) is 95 pm and that of CI ion is 181 pm Predict...

    Text Solution

    |

  3. If the radius of Br^(-) ion is 0.182 nn, how large can a cation be fit...

    Text Solution

    |

  4. A compound AB crystallizes in bcc lattice with unit edge length of 380...

    Text Solution

    |

  5. Tungsten has bcc lattice. Each edge of the unit cell is 316 pm and the...

    Text Solution

    |

  6. Chromium crystallizes in a body centred cubic lattice, whose density i...

    Text Solution

    |

  7. Formula mass of NaCl is 58.45g mol^(-1) and density of its pure form i...

    Text Solution

    |

  8. An element occurs in bcc structure with cell edge 288 pm. Its density ...

    Text Solution

    |

  9. Thallium chloride TlCl crystallises in either a simple cubic lattice o...

    Text Solution

    |

  10. An element (at. mass = 60) having face centred cubic unit cell has a d...

    Text Solution

    |

  11. Analysis shows that a metal oxide has the empirical formula M(0.96) O(...

    Text Solution

    |

  12. Analysis shows that nickel oxide has formula Ni(0.98)O(1.0). What frac...

    Text Solution

    |

  13. Atoms A,B,C and D are present at corners, face centres , body-centres ...

    Text Solution

    |

  14. Which types of Bravais lattice is not present in cubic crystal system ...

    Text Solution

    |

  15. Name the type of crystal systems of NaCl and Borax.

    Text Solution

    |

  16. A cubic unit cell has eight edge-centres. (true/false)

    Text Solution

    |

  17. A compound AB crystallises in bcc lattice with the unit cell edge leng...

    Text Solution

    |

  18. Atoms A,B,C and D are present at edge centres, body-centre, corners an...

    Text Solution

    |

  19. In a HCP unit-cell, if total number of atoms per unit cell gets halved...

    Text Solution

    |

  20. Total number of T-voids and O-voids in HCP and CCP structures are diff...

    Text Solution

    |