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Although Delta(eg)H of fluorine is less ...

Although `Delta_(eg)H` of fluorine is less negative than that of chlorine, but fluorine is a stronger oxidising agent than chlorine. Why?

Text Solution

Verified by Experts

This is due to
(i) Low bond dissociation enthalpy of F-F bond.
(ii) High hydration enthalpy of `F^(-)`.
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(a) Halogens have maximum negative gain enthalpy in the respective periods of the periodic table. Why? (b) Although electron gain enthalpy of fluorine is less negative as compared to chlorine, fluorine is a stronger oxidising agent than chlorine . Why? Fluorine exhibits only-1 oxidation state, wherease other hlaogens exhibit +1,+3,+5, and +7 oxidation states also. explain.

(a) Halogens have maximum negative gain enthalpy in the respective periods of the periodic table. Why? (b) Although electron gain enthalpy of fluorine is less negative as compared to chlorine, fluorine is a stronger oxidising agent than chlorine . Why? Fluorine exhibits only-1 oxidation state, whereas other halogens exhibit +1,+3,+5, and +7 oxidation states also. Explain.

F_(2) is a stronger oxidising agent than Cl_(2)

In aqueous solution , chlorine is a stronger oxidising agent than fluorine.

Explain the following : (a) The electron gain enthalpy with negative sign for fluorine is less than for chlorine, still fluorine is a stronger oxidising agent than chlorine. (b) XeF_(2) is linear molecule without a bend. (c) NCl_(3) is an endothermic compound while NF_(3) is an exothermic one.

Whys is F_(2) a stronger oxidising agent than Cl_(2) ?

What is the oxidising agent in chlorine water ?

Electronegativity of fluorine is greater than that of chlorine.

The bond energy of fluorine is more than that of chlorine.

Fluorine is a better oxidising agent than Cl_2 . It is due to