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Which of the following statement is/are ...

Which of the following statement is/are correct?

A

`B(OH)_(3)` partially reacts with water to form `H_(3)O^(+)` and `[B(OH_(4))]^(-)` and behaves like a weak acid

B

`B(OH)_(3)` behaves like a strong monobasic acid in presence of sugars and this acid can be titrated against NaOH solution using phenolphthalein as an indicator

C

`B(OH)_(3)` does not donate a proton and hence does not form any salt with NaOH

D

`B(OH)_(3)` reacts with NaOH, forming `Na[B(OH)_(4)]`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the statements regarding BOH₃ (orthoboric acid) are correct, we will analyze each statement step by step. ### Step 1: Analyze the first statement **Statement:** BOH₃ partially reacts with water to form H₃O⁺ and BOH₄⁻. BOH₄⁻ behaves like a weak acid. **Analysis:** - When BOH₃ dissolves in water, it can react to form H₃O⁺ and BOH₄⁻. - BOH₄⁻ can indeed act as a weak acid because it can donate a proton (H⁺) in solution. **Conclusion:** This statement is correct. ### Step 2: Analyze the second statement **Statement:** BOH₃ behaves like a strong monobasic acid in the presence of sugar. **Analysis:** - In the presence of sugar, BOH₃ can exhibit stronger acidic behavior due to the formation of complexes. - It can be titrated with NaOH, indicating that it behaves like a strong acid in this context. **Conclusion:** This statement is correct. ### Step 3: Analyze the third statement **Statement:** BOH₃ does not donate a proton and hence does not form any salt with NaOH. **Analysis:** - This statement is incorrect because BOH₃ does donate a proton when it reacts with NaOH. - The reaction with NaOH leads to the formation of NaBO₄, indicating that it does form a salt. **Conclusion:** This statement is incorrect. ### Step 4: Analyze the fourth statement **Statement:** BOH₃ reacts with NaOH to form NaBO₄. **Analysis:** - When BOH₃ reacts with NaOH, it indeed forms NaBO₄. - This confirms that the reaction occurs and a salt is formed. **Conclusion:** This statement is correct. ### Final Conclusion Based on the analysis: - The correct statements are: **A (first statement), B (second statement), and D (fourth statement)**. - The incorrect statement is: **C (third statement)**. ### Summary of Correct Statements - A: Correct - B: Correct - C: Incorrect - D: Correct ### Final Answer: A, B, and D are correct. ---
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