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Statement-1: B(OH)(3) behaves as a lewis...

Statement-1: `B(OH)_(3)` behaves as a lewis acid.
Statement-2: Second ionisation is very much difficult in boric acid.

A

(a) Statement-1 is true, statement-2 is true, statement-2 is a correct explanation for statement-1

B

(b) Statement-1 is true, statement-2 is true, statement-2 is not correct explanation for statement-1

C

(c) Statement-1 is true, statement-2 is false

D

(d) Statement-1 is false, statement-2 is true

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the statements given in the question, we will evaluate each statement step by step. ### Step 1: Evaluate Statement 1 **Statement 1:** B(OH)₃ behaves as a Lewis acid. - **Explanation:** Boric acid (B(OH)₃) has boron as its central atom. Boron has an atomic number of 5, with an electronic configuration of 1s² 2s² 2p¹. In B(OH)₃, boron forms three bonds with hydroxyl (OH) groups. Each bond involves sharing of electrons, leading to a total of 6 electrons around boron (3 from the bonds with OH groups). - **Conclusion:** Since boron has only 6 electrons in its valence shell, it is electron deficient and can accept a pair of electrons, which classifies it as a Lewis acid. Thus, Statement 1 is **True**. ### Step 2: Evaluate Statement 2 **Statement 2:** Second ionization is very much difficult in boric acid. - **Explanation:** Ionization refers to the removal of electrons from an atom. The first ionization of boron (from B(OH)₃) involves removing one electron from the 2p subshell, resulting in a B⁺ ion. The electronic configuration of B⁺ is 1s² 2s² 2p⁰. The second ionization involves removing an electron from the stable B⁺ ion, which has a filled 2s subshell (1s² 2s²). Removing an electron from a stable configuration requires significantly more energy. - **Conclusion:** Therefore, the second ionization is indeed much more difficult compared to the first ionization. Thus, Statement 2 is also **True**. ### Step 3: Determine the Relationship Between the Statements - **Analysis:** While both statements are true, Statement 2 does not serve as a correct explanation for Statement 1. Statement 1 is about the Lewis acidity of boric acid, while Statement 2 discusses the difficulty of the second ionization, which is a separate concept. ### Final Conclusion - Both statements are true, but Statement 2 does not explain Statement 1. Therefore, the correct option is: **Option B:** Statement 1 is true, Statement 2 is true, but Statement 2 is not the correct explanation for Statement 1. ---
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AAKASH INSTITUTE ENGLISH-THE P-BLOCK ELEMENTS-Assignment Section-E)
  1. Statement-1: White P is considered as the elemental state of P. Stat...

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  2. Statement-1: Aluminium chloride has chloro-bridged structure in vapour...

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  3. Statement-1: B(OH)(3) behaves as a lewis acid. Statement-2: Second i...

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  4. Statement-1: B does not form [BF(6)]^(3-) Statement-2: Co-ordination...

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  5. Statement-1: B(2)H(6) on heating with excess of ammonia forms boron ni...

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  6. Statement-1: BCl(3) and C Cl(4) do not undergo hydrolysis. Statement...

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  7. Statement-1: Silicones are used as high class industrial insulators. ...

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  8. Statement-1: Pyro-silicates are 1-D polymers. Statement-2: In pyro-s...

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  9. Statement-1: Inter-stitial carbides are formed when heavy metals react...

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  10. Assertion: All clatharate compound of noble gas are the compounds in w...

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  11. Assertion:PCl(5) is covalent in gaseous and liquid states but ionic in...

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  12. Statement-1: Bond energy of Hl is smaller than that of HBr. Statemen...

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  13. Statement-1: NCl(3) is hydrolysed by water by NF(3) is not hydrolysed....

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  14. Statement-1: Peroxomonosulphuric acid has low basicity. Statement-2:...

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  15. Statement-1: HF is weaker acid than HCl. Statement-2: F^(-) has high...

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  16. Statement-1: IC l(2)^(Theta) is a linear compound. Statement-2: In I...

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  17. Statement-1: NH(3) is more basic than NF(3) Statement-2: F is more e...

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  18. Statement-1: H(2)S is weak diprotic acid. Statement-2: Salt of aq. N...

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  19. Statement-1: All noble gases are considered as unreactive. Statement...

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  20. Statement-1: NH(4)NO(3) evolve a gas on addition of NaOH. Statement-...

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