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One mole of KClO(3) is heated in presenc...

One mole of `KClO_(3)` is heated in presence of `MnO_(2)`. The produced oxygen is used in burning of Al. Then oxide of Al that will be formed.

A

2 mole

B

1 mole

C

4 mole

D

3 mole

Text Solution

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The correct Answer is:
To solve the problem step by step, we will follow the chemical reactions involved and the stoichiometry of the reactants and products. ### Step 1: Decomposition of KClO₃ When potassium chlorate (KClO₃) is heated in the presence of manganese dioxide (MnO₂), it decomposes to form potassium chloride (KCl) and oxygen (O₂). The balanced equation for this reaction is: \[ 2 \text{KClO}_3 \xrightarrow{\text{heat}, \text{MnO}_2} 2 \text{KCl} + 3 \text{O}_2 \] From the equation, we can see that 2 moles of KClO₃ produce 3 moles of O₂. Therefore, 1 mole of KClO₃ will produce: \[ \text{O}_2 \text{ produced} = \frac{3}{2} \text{ moles of O}_2 \] ### Step 2: Reaction of Oxygen with Aluminum Now, the produced oxygen (O₂) will react with aluminum (Al) to form aluminum oxide (Al₂O₃). The balanced equation for this reaction is: \[ 4 \text{Al} + 3 \text{O}_2 \rightarrow 2 \text{Al}_2\text{O}_3 \] ### Step 3: Determine Moles of Aluminum Oxide Formed From the reaction, we can see that 3 moles of O₂ react with 4 moles of Al to produce 2 moles of Al₂O₃. We need to find out how many moles of Al₂O₃ can be produced from the oxygen generated from 1 mole of KClO₃. Since 1 mole of KClO₃ produces \( \frac{3}{2} \) moles of O₂, we can set up a proportion to find the moles of Al₂O₃ produced: Using the stoichiometry from the reaction of Al with O₂: \[ \frac{3 \text{ moles O}_2}{2 \text{ moles Al}_2\text{O}_3} \] We can calculate the moles of Al₂O₃ produced from \( \frac{3}{2} \) moles of O₂: \[ \text{Moles of Al}_2\text{O}_3 = \frac{2}{3} \times \frac{3}{2} = 1 \text{ mole of Al}_2\text{O}_3 \] ### Conclusion Thus, the oxide of aluminum that will be formed is: \[ \text{Al}_2\text{O}_3 \]
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