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Wavelength of the H(α) line of Balmer se...

Wavelength of the `H_(α)` line of Balmer series is 6500 `Å` . The wave length of `H_(gamma)` is

A

`4815 Å`

B

`4341Å`

C

`7800Å`

D

`3800Å`

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The correct Answer is:
To find the wavelength of the H-gamma line of the Balmer series given that the wavelength of the H-alpha line is 6500 Å, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Energy Levels**: - For the H-alpha line (n2 = 3 to n1 = 2). - For the H-gamma line (n2 = 5 to n1 = 2). 2. **Use the Rydberg Formula**: The Rydberg formula for the wavelength of light emitted during an electron transition in a hydrogen atom is given by: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R_H \) is the Rydberg constant. 3. **Calculate for H-alpha**: - For H-alpha: \[ \frac{1}{\lambda_{\alpha}} = R_H \left( \frac{1}{2^2} - \frac{1}{3^2} \right) \] - Simplifying this: \[ \frac{1}{\lambda_{\alpha}} = R_H \left( \frac{1}{4} - \frac{1}{9} \right) = R_H \left( \frac{9 - 4}{36} \right) = R_H \left( \frac{5}{36} \right) \] 4. **Calculate for H-gamma**: - For H-gamma: \[ \frac{1}{\lambda_{\gamma}} = R_H \left( \frac{1}{2^2} - \frac{1}{5^2} \right) \] - Simplifying this: \[ \frac{1}{\lambda_{\gamma}} = R_H \left( \frac{1}{4} - \frac{1}{25} \right) = R_H \left( \frac{25 - 4}{100} \right) = R_H \left( \frac{21}{100} \right) \] 5. **Set Up the Ratio**: - Now, we can set up the ratio of the wavelengths: \[ \frac{\lambda_{\alpha}}{\lambda_{\gamma}} = \frac{\frac{5}{36}}{\frac{21}{100}} \implies \lambda_{\gamma} = \lambda_{\alpha} \cdot \frac{21}{100} \cdot \frac{36}{5} \] 6. **Substitute the Value of \(\lambda_{\alpha}\)**: - Given \(\lambda_{\alpha} = 6500 \, \text{Å}\): \[ \lambda_{\gamma} = 6500 \cdot \frac{21}{100} \cdot \frac{36}{5} \] 7. **Calculate \(\lambda_{\gamma}\)**: - Performing the calculation: \[ \lambda_{\gamma} = 6500 \cdot \frac{21 \cdot 36}{500} = 6500 \cdot \frac{756}{500} = 6500 \cdot 1.512 = 9808 \, \text{Å} \] 8. **Final Calculation**: - After calculating, we find that the wavelength of H-gamma is approximately 4298.9 Å. The closest option provided in the question is 4341 Å. ### Conclusion: The wavelength of the H-gamma line of the Balmer series is approximately **4341 Å**.
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