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The total spin resulting from d^(9) con...

The total spin resulting from `d^(9)` configuration is

A

`(9)/( 2)`

B

2

C

`(5)/(2)`

D

`(1)/(2)`

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AI Generated Solution

The correct Answer is:
To find the total spin resulting from a \( d^9 \) configuration, we can follow these steps: ### Step 1: Understand the \( d \) orbital configuration The \( d \) subshell can hold a maximum of 10 electrons, as it consists of 5 orbitals (each can hold 2 electrons). In the case of \( d^9 \), there are 9 electrons present in the \( d \) subshell. ### Step 2: Fill the \( d \) orbitals When filling the \( d \) orbitals, we follow Hund's rule, which states that electrons will fill degenerate orbitals singly first before pairing up. The filling of the \( d \) orbitals with 9 electrons would look like this: - Each of the 5 \( d \) orbitals will first receive 1 electron (5 electrons total). - The next 4 electrons will pair up with the first 4 orbitals, resulting in 4 paired electrons and 1 unpaired electron. ### Step 3: Determine the spin of the electrons - Each electron has a spin of \( +\frac{1}{2} \) or \( -\frac{1}{2} \). - In the \( d^9 \) configuration, we have: - 4 paired electrons: Each pair contributes \( +\frac{1}{2} \) and \( -\frac{1}{2} \), resulting in a net spin of 0 for these electrons. - 1 unpaired electron: This contributes a spin of \( +\frac{1}{2} \). ### Step 4: Calculate the total spin The total spin is the sum of the spins of all the electrons: - Total spin = Spin from paired electrons + Spin from unpaired electron - Total spin = \( 0 + \frac{1}{2} = \frac{1}{2} \) ### Conclusion Thus, the total spin resulting from the \( d^9 \) configuration is \( \frac{1}{2} \). ### Final Answer The correct answer is \( \frac{1}{2} \). ---
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