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An electron is moving in 3^(rd) orbit of...

An electron is moving in `3^(rd)` orbit of `Li^(+2)` and its separation energy is y.The separation energy of an electron moving in `2^(nd)` orbit of `He^(+)` is

A

`(4y)/( 9)`

B

`(y)/(9)`

C

`-(y)/(9)`

D

`y`

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The correct Answer is:
To solve the problem, we need to determine the separation energy of an electron moving in the second orbit of the helium ion \( \text{He}^+ \), given that the separation energy of an electron in the third orbit of lithium ion \( \text{Li}^{2+} \) is \( y \). ### Step-by-Step Solution: 1. **Understand Separation Energy**: The separation energy is the energy required to remove an electron from an atom or ion. It can be calculated using the formula for the energy of an electron in a given orbit. 2. **Energy Formula**: The energy of an electron in an orbit is given by the formula: \[ E_n = -\frac{13.6 \, \text{eV} \cdot Z^2}{n^2} \] where \( Z \) is the atomic number and \( n \) is the principal quantum number (orbit number). 3. **Calculate Separation Energy for \( \text{Li}^{2+} \)**: - For lithium (\( Z = 3 \)) in the third orbit (\( n = 3 \)): \[ E_3 = -\frac{13.6 \cdot 3^2}{3^2} = -\frac{13.6 \cdot 9}{9} = -13.6 \, \text{eV} \] - The energy at infinity \( E_\infty \) is \( 0 \, \text{eV} \). - Therefore, the separation energy \( y \) is: \[ y = E_\infty - E_3 = 0 - (-13.6) = 13.6 \, \text{eV} \] 4. **Calculate Separation Energy for \( \text{He}^+ \)**: - For helium (\( Z = 2 \)) in the second orbit (\( n = 2 \)): \[ E_2 = -\frac{13.6 \cdot 2^2}{2^2} = -\frac{13.6 \cdot 4}{4} = -13.6 \, \text{eV} \] - Again, the energy at infinity \( E_\infty \) is \( 0 \, \text{eV} \). - Therefore, the separation energy for helium is: \[ \text{Separation Energy} = E_\infty - E_2 = 0 - (-13.6) = 13.6 \, \text{eV} \] 5. **Relate to \( y \)**: Since we found that the separation energy of the electron in the second orbit of \( \text{He}^+ \) is also \( 13.6 \, \text{eV} \), and we previously established that \( y = 13.6 \, \text{eV} \), we conclude: \[ \text{Separation Energy for } \text{He}^+ = y \] ### Final Answer: The separation energy of an electron moving in the second orbit of \( \text{He}^+ \) is \( y \).
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