Home
Class 12
CHEMISTRY
When the common salt dissolves in water,...

When the common salt dissolves in water, the entropy of the system increases. This means that the sign of `Delta`S is ______ and randomness of the system _______

A

Undetermined, increases

B

Positive, decreases

C

Positive, increases

D

Negative, decreases

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the process of dissolving common salt (sodium chloride, NaCl) in water and its effect on entropy and randomness. ### Step-by-Step Solution: 1. **Understanding the Dissolution Process**: - When common salt (NaCl) dissolves in water, it dissociates into its constituent ions: Na⁺ and Cl⁻. This process transforms the solid salt into ions that are dispersed in the liquid water. 2. **State of Matter Change**: - The salt starts as a solid, where the ions are closely packed in a crystalline structure. Upon dissolving, these ions are released into the liquid phase, where they are more spread out and free to move. 3. **Entropy and Randomness**: - Entropy (ΔS) is a measure of the disorder or randomness of a system. In this case, the transition from a solid state (low entropy, ordered structure) to a liquid state (high entropy, disordered structure) indicates an increase in randomness. 4. **Sign of Change in Entropy**: - Since the randomness of the system increases when the salt dissolves, the change in entropy (ΔS) is positive. A positive ΔS indicates that the system has become more disordered. 5. **Conclusion**: - Therefore, we conclude that the sign of ΔS is positive, and the randomness of the system increases. ### Final Answer: The sign of ΔS is **positive** and the randomness of the system **increases**.
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    AAKASH INSTITUTE ENGLISH|Exercise SECTION-B|20 Videos
  • THERMODYNAMICS

    AAKASH INSTITUTE ENGLISH|Exercise SECTION-C|13 Videos
  • THERMODYNAMICS

    AAKASH INSTITUTE ENGLISH|Exercise TRY YOURSELF|66 Videos
  • THE SOLID STATE

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (SECTION - D) (ASSERTION-REASON TYPE QUESTION)|20 Videos

Similar Questions

Explore conceptually related problems

When common salt is dissolved in water

If common salt is dissolved in water, the vapour pressure of the solution will

Which one of the following salts when dissolves in water hydrolyse?

The least random state of water system is

When temperature increases dissolved oxygen of water

A gas X when dissolved in water, heat is evolved. Then solubility of X will increases at

Which correctly represents the entropy (s) of an isolated system during a process.

Entropy is a measure of randomess of system. When a liquid is converted to the vapour state entropy of the system increases. Entropy in the phase transformation is calculated using Delta S = (Delta H)/(T) but in reversible adiabatic process Delta S will be zero. The rise in temperature in isobaric or isochoric process increases the randomness of system, which is given by Delta S = "2.303 n C log"((T_(2))/(T_(1))) C = C_(P) or C_(V) Entropy change in a reversible adiabatic process is

Entropy is a measure of randomess of system. When a liquid is converted to the vapour state entropy of the system increases. Entropy in the phase transformation is calculated using Delta S = (Delta H)/(T) but in reversible adiabatic process Delta S will be zero. The rise in temperature in isobaric or isochoric process increases the randomness of system, which is given by Delta S = "2.303 n C log"((T_(2))/(T_(1))) C = C_(P) or C_(V) The change in entropy when 1 mole O_(2) gas expands isothermally and reversibly from an initial volume 1 litre to a final volume 100 litre at 27^(@)C

Entropy is a measure of randomess of system. When a liquid is converted to the vapour state entropy of the system increases. Entropy in the phase transformation is calculated using Delta S = (Delta H)/(T) but in reversible adiabatic process Delta S will be zero. The rise in temperature in isobaric or isochoric process increases the randomness of system, which is given by Delta S = "2.303 n C log"((T_(2))/(T_(1))) C = C_(P) or C_(V) The temperature at whicgh liquid H_(2)O will be in equrilibrium with its vapour is ( Delta H and Delta S for vapourisation are 50 kJ mol^(-1) and 0.15 kJ mol^(-1)K^(-1) )

AAKASH INSTITUTE ENGLISH-THERMODYNAMICS-SECTION-A
  1. A reaction occurs spontaneously in forward direction if

    Text Solution

    |

  2. For an exothermic reaction to be spontaneous (DeltaS = negative)

    Text Solution

    |

  3. The enthalpy change of a reaction does not depend on

    Text Solution

    |

  4. The free energy change for a reversible reaction at equilibrium is: ...

    Text Solution

    |

  5. In a chemical reaction, Delta H = 150 kJ and Delta S = 100 JK^(-1) at ...

    Text Solution

    |

  6. Pick out the correct option which represents for the work done by the ...

    Text Solution

    |

  7. A gas expands isothermally against a constant external pressure of 1 a...

    Text Solution

    |

  8. The free energy change, DeltaG = 0, when

    Text Solution

    |

  9. If an insulated container containing liquid is stirred with a paddle t...

    Text Solution

    |

  10. If the bond energies of H-H, Br-Br and H-Br are 433, 192 and 364 KJ "m...

    Text Solution

    |

  11. If one mole of ammonia and one mole of hydrogen chloride are mixed in ...

    Text Solution

    |

  12. In thermodynamics, a process is called reversible when

    Text Solution

    |

  13. X(g) + 2Y(g) rarr 2Z(g) + 3A(g) The change in enthalpy at 27^(@)C is 7...

    Text Solution

    |

  14. In a spontaneous process the system undergoes

    Text Solution

    |

  15. A quantity of an ideal gas at 20^(@)C reversibly expands against a con...

    Text Solution

    |

  16. When the common salt dissolves in water, the entropy of the system inc...

    Text Solution

    |

  17. Pick the extensive property from the given options

    Text Solution

    |

  18. If a process is both endothermic and spontaneous then

    Text Solution

    |

  19. The specific heat of gas is found to be 0.075 calories at constant vol...

    Text Solution

    |

  20. The standard entropies of N(2)(g),H(2)(g) and NH(3)(g) are 191.5, 130....

    Text Solution

    |