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If K(1) and K(2) are respective equilib...

If `K_(1)` and `K_(2)` are respective equilibrium constants for two reactions `:`
`XeF_(6)(g) +H_(2)O hArr XeOF_(4)(g) +2HF(g)`
`XeO_(4)(g)+XeF_(6)(g)hArr XeOF_(4)(g)+XeO_(3)F_(2)(g)`
Then equilibrium constant for the reaction
`XeO_(4)(g)+2HF(g) hArr XeO_(3)F_(2)(g)+H_(2)O(g)` will be

A

`(K_(1))/(K_(2)^(2))`

B

`K_(1)K_(2)`

C

`(K_(1))/(K_(2))`

D

`(K_(2))/(K_(1))`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the equilibrium constant for the reaction: \[ \text{XeO}_4(g) + 2\text{HF}(g) \rightleftharpoons \text{XeO}_3\text{F}_2(g) + \text{H}_2\text{O}(g) \] using the given equilibrium constants \( K_1 \) and \( K_2 \) for the two reactions: 1. \[ \text{XeF}_6(g) + \text{H}_2\text{O}(g) \rightleftharpoons \text{XeOF}_4(g) + 2\text{HF}(g) \] with equilibrium constant \( K_1 \) 2. \[ \text{XeO}_4(g) + \text{XeF}_6(g) \rightleftharpoons \text{XeOF}_4(g) + \text{XeO}_3\text{F}_2(g) \] with equilibrium constant \( K_2 \) ### Step-by-Step Solution: **Step 1: Write the expressions for \( K_1 \) and \( K_2 \)** For the first reaction: \[ K_1 = \frac{[\text{XeOF}_4][\text{HF}]^2}{[\text{XeF}_6][\text{H}_2\text{O}]} \] For the second reaction: \[ K_2 = \frac{[\text{XeOF}_4][\text{XeO}_3\text{F}_2]}{[\text{XeO}_4][\text{XeF}_6]} \] **Step 2: Rearrange the second reaction to isolate \(\text{XeF}_6\)** From the second reaction, we can express \([\text{XeF}_6]\) in terms of the other species: \[ [\text{XeF}_6] = \frac{[\text{XeOF}_4][\text{XeO}_3\text{F}_2]}{K_2[\text{XeO}_4]} \] **Step 3: Substitute \([\text{XeF}_6]\) into the \( K_1 \) expression** Now, we substitute \([\text{XeF}_6]\) into the expression for \( K_1 \): \[ K_1 = \frac{[\text{XeOF}_4][\text{HF}]^2}{\left(\frac{[\text{XeOF}_4][\text{XeO}_3\text{F}_2]}{K_2[\text{XeO}_4]}\right)[\text{H}_2\text{O}]} \] **Step 4: Simplify the expression** Rearranging gives: \[ K_1 = \frac{K_2[\text{XeO}_4][\text{HF}]^2}{[\text{XeOF}_4][\text{XeO}_3\text{F}_2][\text{H}_2\text{O}]} \] **Step 5: Rearranging for \( K_3 \)** Now we want to express \( K_3 \) for the desired reaction: \[ K_3 = \frac{[\text{XeO}_3\text{F}_2][\text{H}_2\text{O}]}{[\text{XeO}_4][\text{HF}]^2} \] From the rearranged \( K_1 \), we can see that: \[ K_3 = \frac{K_2}{K_1} \] **Step 6: Final expression for \( K_3 \)** Thus, the equilibrium constant for the reaction \( \text{XeO}_4(g) + 2\text{HF}(g) \rightleftharpoons \text{XeO}_3\text{F}_2(g) + \text{H}_2\text{O}(g) \) is: \[ K_3 = \frac{K_2}{K_1} \] ### Conclusion The answer to the question is: \[ K_3 = \frac{K_2}{K_1} \]
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AAKASH INSTITUTE ENGLISH-EQUILIBRIUM-Assignment (SECTION-A) (SUBJECTIVE TYPE QUESTIONS(ONE OPTION IS CORRECT)
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  2. If pressure is increased on the equlibrium N(2)+O(2)hArr2NO the equlib...

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  3. If K(1) and K(2) are respective equilibrium constants for two reactio...

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  4. For the reaction CO(g)+(1)/(2) O(2)(g) hArr CO(2)(g),K(p)//K(c) is

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  5. 500 ml vessel contains 1.5 M each of A, B, C and D at equlibrium. If 0...

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  6. 9.2 grams of N(2)O(4(g)) is taken in a closed one litre vessel and hea...

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  7. For the synthesis of ammonia by the reaction N(2)+3H(2)hArr2NH(3) in t...

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  8. The equilibrium: P(4)(g)+6Cl(2)(g) hArr 4PCl(3)(g) is attained by ...

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  9. For the hypothetical reactions, the equilibrium constant (K) value are...

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  10. Partial pressure of O(2) in the reaction 2Ag(2)O(s) hArr 4Ag(s)+O(2)...

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  11. For the following gases equilibrium, N(2)O(4)(g)hArr2NO(2)(g) K(p) i...

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  12. NH(4)COONH(2)(s)hArr2NH(3)(g)+CO(2)(g) If equilibrium pressure is 3 at...

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  13. The following two reactions: i. PCl(5)(g) hArr PCl(3)(g)+Cl(2)(g) ...

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  14. When hydrogen molecules decompose into its atoms, which conditions giv...

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  15. Equilivalent amounts of H(2) and I(2) are heated in a closed vessel ti...

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  16. The dissociation constants for acetic acid and HCN at 25^(@)C are 1.5x...

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  17. Hg(2)Cl(2)(g) in saturated aqeous solution has equilibrium constant eq...

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  18. K(rho) for the following reaction will be equal to 3Fe(s)+4H(2)O(g)hAr...

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  19. Which of the following factors will favour the reverse reaction in a c...

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  20. The pH of 10^(-8)M solution of HCl in water is

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