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pH is the negative logarithm of H^(+) ...

pH is the negative logarithm of `H^(+)`
` pH=log[H^(+)]`
`HCllt H^(+)+Cl^(-)`
`H_(2)OhArrH^(+)+OH^(-)`
` K_(W)=[H^(+)][OH^(-)]`
`K_(W)` depend on the temperatue. With rise in temperature `K_(W)` increases.
At 298 K, pH of pure water = 7
The exact concentration of `H^(+)` in `10^(-6)` M HCl given by

A

`10^(-6)+10^(-8)`

B

`10^(-6)+10^(-7)`

C

`10^(-6)`

D

`10^(-6)-10^(-7)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the total concentration of \( H^+ \) ions in a solution of \( 10^{-6} \) M HCl. ### Step-by-Step Solution: 1. **Understanding pH and \( H^+ \) Concentration**: - The pH of a solution is defined as: \[ \text{pH} = -\log[H^+] \] - At 298 K, pure water has a pH of 7, which means: \[ [H^+] = 10^{-7} \text{ M} \] 2. **Dissociation of HCl**: - When \( HCl \) is dissolved in water, it dissociates completely: \[ HCl \rightarrow H^+ + Cl^- \] - Therefore, a \( 10^{-6} \) M solution of \( HCl \) will contribute \( 10^{-6} \) M of \( H^+ \) ions. 3. **Total Concentration of \( H^+ \)**: - The total concentration of \( H^+ \) ions in the solution will be the sum of the \( H^+ \) ions contributed by \( HCl \) and those from the ionization of water: \[ [H^+]_{\text{total}} = [H^+]_{\text{HCl}} + [H^+]_{\text{water}} \] - Substituting the known values: \[ [H^+]_{\text{total}} = 10^{-6} \text{ M} + 10^{-7} \text{ M} \] 4. **Calculating the Total Concentration**: - To add these two concentrations, we can express \( 10^{-6} \) M as \( 1.0 \times 10^{-6} \) M and \( 10^{-7} \) M as \( 0.1 \times 10^{-6} \) M: \[ [H^+]_{\text{total}} = 1.0 \times 10^{-6} + 0.1 \times 10^{-6} = 1.1 \times 10^{-6} \text{ M} \] 5. **Conclusion**: - The total concentration of \( H^+ \) ions in the \( 10^{-6} \) M HCl solution is: \[ [H^+]_{\text{total}} = 1.1 \times 10^{-6} \text{ M} \] ### Final Answer: The exact concentration of \( H^+ \) in \( 10^{-6} \) M HCl is \( 1.1 \times 10^{-6} \) M. ---
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