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STATEMENT-1: For H(2)O(l)hArrH(2)O(g) va...

STATEMENT-1: For `H_(2)O(l)hArrH_(2)O(g)` vapour pressure if P atm then `K_(rho)` is equal to vapour pressure
STATEMENT-2:` K_(rho)` can be changed by adding more `H_(2)O` vapour from our side

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-9

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-9

C

Statement-1 is True, Statement-2 is False

D

Statement-1 is False, Statement-2 is True

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the two statements provided and determine their validity based on the principles of chemical equilibrium. ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction given is: \[ H_2O(l) \rightleftharpoons H_2O(g) \] This represents the equilibrium between liquid water and water vapor. 2. **Equilibrium Constant \( K_p \)**: The equilibrium constant \( K_p \) for this reaction is defined as: \[ K_p = \frac{P_{H_2O(g)}}{P_{H_2O(l)}} \] However, since the concentration of a pure liquid (like \( H_2O(l) \)) does not appear in the equilibrium expression, we can simplify this to: \[ K_p = P_{H_2O(g)} \] where \( P_{H_2O(g)} \) is the vapor pressure of water. 3. **Evaluating Statement 1**: Statement 1 claims that for the equilibrium \( H_2O(l) \rightleftharpoons H_2O(g) \), if the vapor pressure is \( P \) atm, then \( K_p \) is equal to the vapor pressure. - This statement is **true** because we have established that \( K_p = P_{H_2O(g)} \) which is equal to the vapor pressure. 4. **Evaluating Statement 2**: Statement 2 states that \( K_p \) can be changed by adding more \( H_2O \) vapor from our side. - This statement is **false**. The equilibrium constant \( K_p \) is only affected by changes in temperature. Adding more \( H_2O(g) \) will shift the equilibrium position but will not change the value of \( K_p \). Instead, it will lead to a change in the concentrations of the reactants and products until a new equilibrium is established. 5. **Conclusion**: - Statement 1 is true. - Statement 2 is false. Thus, the correct answer is that Statement 1 is true and Statement 2 is false. ### Final Answer: - Statement 1: True - Statement 2: False
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