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The hydrolysis of ethylmethanoate is slo...

The hydrolysis of ethylmethanoate is slow in
beginning and becomes faster after some time as it
is autocatalysed by

A

Methanol

B

Ethanol

C

Methanoic acid

D

Ethanoic acid

Text Solution

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The correct Answer is:
To solve the question regarding the hydrolysis of ethyl methanoate and its autocatalysis, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Hydrolysis of Esters**: - Hydrolysis of an ester involves the reaction of the ester with water to produce an acid and an alcohol. The general reaction can be represented as: \[ RCOOR' + H_2O \rightarrow RCOOH + R'OH \] - In this case, ethyl methanoate (HCOOC2H5) will hydrolyze to form methanoic acid (HCOOH) and ethanol (C2H5OH). 2. **Identifying the Products**: - When ethyl methanoate undergoes hydrolysis: \[ HCOOC2H5 + H_2O \rightarrow HCOOH + C2H5OH \] - The products are methanoic acid (HCOOH) and ethanol (C2H5OH). 3. **Understanding Autocatalysis**: - Autocatalysis occurs when one of the products of a reaction acts as a catalyst for that same reaction. In this case, methanoic acid, which is formed during the hydrolysis, can act as a catalyst. - Initially, the reaction is slow because there are no products to catalyze it. As methanoic acid is produced, it increases the rate of the reaction by providing H+ ions, which facilitate further hydrolysis. 4. **Conclusion**: - Since methanoic acid is produced during the hydrolysis of ethyl methanoate and acts as a catalyst for the reaction, it is the autocatalyst in this process. - Therefore, the correct answer to the question is **option C: methanoic acid**.
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