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The co-ordination number of Co in [Co(C(...

The co-ordination number of Co in `[Co(C_(2)O_(4))_(2)Cl_(2)]` is

A

4

B

6

C

8

D

12

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AI Generated Solution

The correct Answer is:
To determine the coordination number of cobalt in the complex `[Co(C₂O₄)₂Cl₂]`, we can follow these steps: ### Step 1: Identify the ligands in the complex In the given complex, we have two types of ligands: - Oxalate ion (C₂O₄²⁻), which is a bidentate ligand. - Chloride ion (Cl⁻), which is a monodentate ligand. ### Step 2: Determine the contribution of each ligand to the coordination number - **Bidentate ligands**: Each oxalate ion can bind to the cobalt ion at two sites. Since there are two oxalate ions, they contribute: \[ 2 \text{ (from one oxalate)} \times 2 \text{ (number of oxalates)} = 4 \] - **Monodentate ligands**: Each chloride ion binds at one site. Since there are two chloride ions, they contribute: \[ 1 \text{ (from one chloride)} \times 2 \text{ (number of chlorides)} = 2 \] ### Step 3: Calculate the total coordination number Now, we add the contributions from both types of ligands: \[ \text{Total Coordination Number} = 4 \text{ (from oxalates)} + 2 \text{ (from chlorides)} = 6 \] ### Conclusion Thus, the coordination number of cobalt in the complex `[Co(C₂O₄)₂Cl₂]` is **6**. ---
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AAKASH INSTITUTE ENGLISH-COORDINATION COMPOUNDS -Assignment (Section-A Objective type Questions (One Option is correct))
  1. The IUPAC name of [Ni(CN)(4)]^(2-) is

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  2. Out of following which ligand is a pi acid ligand ?

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  3. The co-ordination number of Co in [Co(C(2)O(4))(2)Cl(2)] is

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  4. Which of the following is not an ambidntate ligand ?

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  5. Primary and secondary valencies of Cu in [Cu(NH(3))(4)]SO(4) is

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  6. IUPAC name of K[BF(4)]

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  7. Oxidation number of plantinum in cis-platin

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  8. Aq. solution of of KCl * MgCl(2) * 6H(2)O will give test of

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  9. Which of the following complex is homoleptic ?

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  10. Aqueous solution of CoCl(3)*6NH(3) upon addition with AgNO(3) produces...

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  11. Structural formula of tetraaquadichloridochromium(III) chloride

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  12. Which of the following is neutral coordination sphere ?

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  13. Which of the following is not a polydentate ligand ?

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  14. Find the incorrect statement about EDTA

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  15. The complex [Cr(H(2)O)(5)Cl]Br and [Cr(H(2)O)(5)Br]Cl show

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  16. Which of the following octahedral complexes do not show geometrical i...

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  17. The number of geometical isomers possible for a square planar complex ...

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  18. The comopound which exhibits coordination isomerism is:

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  19. Which one of the following complexes will have six isomers ?

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  20. Which of the following does not show optical activity ?

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