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[Cr(CN)(6)][Co(NH(3))(6)] contains...

`[Cr(CN)_(6)][Co(NH_(3))_(6)]` contains

A

Cationic complex

B

Anionic complex

C

Neutral ligands

D

Anionic ligands

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the coordination compound \([Cr(CN)_{6}][Co(NH_{3})_{6}]\), we will break it down step by step. ### Step 1: Identify the components of the complex The given complex is made up of two parts: \([Cr(CN)_{6}]\) and \([Co(NH_{3})_{6}]\). ### Step 2: Determine the charge of each complex 1. **For \([Cr(CN)_{6}]\)**: - The cyanide ion (CN) has a charge of -1. - Since there are 6 cyanide ions, the total negative charge contributed by CN is \(6 \times (-1) = -6\). - To balance this charge, chromium must have an oxidation state of +3 (since -6 + 3 = -3, which is the overall charge of the complex). - Therefore, \([Cr(CN)_{6}]\) has a charge of -3. 2. **For \([Co(NH_{3})_{6}]\)**: - Ammonia (NH3) is a neutral ligand, contributing no charge. - Therefore, cobalt must have an oxidation state of +3 to balance the overall charge of the complex. - Hence, \([Co(NH_{3})_{6}]\) has a charge of +3. ### Step 3: Identify the overall charge of the coordination compound The overall coordination compound is neutral because it consists of a cationic complex \([Co(NH_{3})_{6}]^{3+}\) and an anionic complex \([Cr(CN)_{6}]^{3-}\). ### Step 4: Classify the ligands - **Cyanide (CN)**: This is an anionic ligand because it carries a negative charge. - **Ammonia (NH3)**: This is a neutral ligand because it carries no charge. ### Conclusion Based on the analysis: - The complex contains both cationic and anionic components. - It has both neutral ligands (NH3) and anionic ligands (CN). ### Final Answer The coordination compound \([Cr(CN)_{6}][Co(NH_{3})_{6}]\) contains: - Cationic complex: Yes - Anionic complex: Yes - Neutral ligands: Yes - Anionic ligands: Yes
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