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The number of sigma and pi-bonds in but-...

The number of `sigma` and `pi`-bonds in but-1-en-3-yne are

A

5 sigma and 5 pi

B

7 sigma and 3 pi

C

8 sigma and 2 pi

D

6 sigma and 4 pi

Text Solution

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The correct Answer is:
To determine the number of sigma (σ) and pi (π) bonds in but-1-en-3-yne, we first need to draw its structural formula based on the name. ### Step 1: Draw the Structure 1. **Identify the Carbon Backbone**: The name "but" indicates that there are 4 carbon atoms. 2. **Identify the Functional Groups**: "1-en" indicates a double bond between the first and second carbon atoms, and "3-yne" indicates a triple bond starting from the third carbon atom. The structure can be represented as follows: ``` H H | | H--C==C--C≡C--H | | H H ``` ### Step 2: Count the Sigma Bonds - **Single Bonds**: Each single bond is a sigma bond. - **Double Bonds**: A double bond consists of one sigma bond and one pi bond. - **Triple Bonds**: A triple bond consists of one sigma bond and two pi bonds. Now, let's count the sigma bonds: - **Between C1 and C2**: 1 sigma bond (in the double bond) - **Between C2 and C3**: 1 sigma bond (in the double bond) - **Between C3 and C4**: 1 sigma bond (in the triple bond) - **Between C1 and H**: 3 sigma bonds (C1 has 3 H atoms) - **Between C2 and H**: 2 sigma bonds (C2 has 2 H atoms) - **Between C3 and H**: 1 sigma bond (C3 has 1 H atom) - **Between C4 and H**: 1 sigma bond (C4 has 1 H atom) Total sigma bonds: - 1 (C1-C2) + 1 (C2-C3) + 1 (C3-C4) + 3 (C1-H) + 2 (C2-H) + 1 (C3-H) + 1 (C4-H) = 10 sigma bonds. ### Step 3: Count the Pi Bonds - **Double Bond (C1=C2)**: 1 pi bond - **Triple Bond (C3≡C4)**: 2 pi bonds Total pi bonds: - 1 (from double bond) + 2 (from triple bond) = 3 pi bonds. ### Final Count - **Total Sigma Bonds**: 7 - **Total Pi Bonds**: 3 ### Answer The number of sigma (σ) and pi (π) bonds in but-1-en-3-yne are: - **Sigma Bonds**: 7 - **Pi Bonds**: 3
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