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Which one is preferable reagent for gi...

Which one is preferable reagent for given reaction ?
` R CH_(2)-X to HO - CH_(2) R`

A

`(H_(2)O+KOH)`

B

`(ROH + KOH)`

C

`(ROH + KOH) // Delta`

D

`(H_(2)O + KOH )//Delta`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the preferable reagent for the reaction \( RCH_2X \rightarrow HOCH_2R \), we need to analyze the given options and the nature of the reaction. ### Step-by-Step Solution: 1. **Identify the Reaction Type**: - The reaction involves the conversion of an alkyl halide (\( RCH_2X \)) to an alcohol (\( HOCH_2R \)). This indicates a nucleophilic substitution reaction where the halide (\( X \)) is replaced by a hydroxyl group (\( OH \)). 2. **Examine the Reagents**: - The options provided are: - A) \( H_2O + KOH \) - B) \( ROH + KOH \) - C) \( ROH + KOH \) (with heat) - D) \( H_2O + KOH \) (with heat) 3. **Consider the Nature of the Reagents**: - **Aqueous KOH (\( H_2O + KOH \))**: This is a strong base that provides hydroxide ions (\( OH^- \)). It favors nucleophilic substitution reactions, making it suitable for converting alkyl halides to alcohols. - **Alcoholic KOH (\( ROH + KOH \))**: This tends to favor elimination reactions (formation of alkenes) rather than substitution, which is not suitable for this reaction. - **Heating with Alcoholic KOH**: Heating will further promote elimination reactions, making it less favorable for producing alcohol. - **Heating with Aqueous KOH**: While heating can sometimes help in certain reactions, in this case, the aqueous KOH alone is sufficient for the nucleophilic substitution. 4. **Conclusion**: - The preferable reagent for the reaction \( RCH_2X \rightarrow HOCH_2R \) is **Aqueous KOH** (\( H_2O + KOH \)), as it effectively facilitates the nucleophilic substitution to form the alcohol. ### Final Answer: The preferable reagent for the reaction is **Aqueous KOH** (\( H_2O + KOH \)). ---

To determine the preferable reagent for the reaction \( RCH_2X \rightarrow HOCH_2R \), we need to analyze the given options and the nature of the reaction. ### Step-by-Step Solution: 1. **Identify the Reaction Type**: - The reaction involves the conversion of an alkyl halide (\( RCH_2X \)) to an alcohol (\( HOCH_2R \)). This indicates a nucleophilic substitution reaction where the halide (\( X \)) is replaced by a hydroxyl group (\( OH \)). 2. **Examine the Reagents**: ...
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