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R- overset(18)(OH) + R overset(O)overset...

`R- overset(18)(OH) + R overset(O)overset(||)(C ) -OH overset(H) (to)`
Products are

A

`R- overset(O)overset(||)(C ) -overset(18)(O) R + H_(2)O`

B

`R- overset(O)overset(||)(C ) -OR +H_(2)^(18)O`

C

`R-overset(O)overset(||)(C ) - OR + H_(2)^(18)O`

D

`R- overset(O)overset(||)(C )- overset(18)(OR) +H_(2)O`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the reaction between an alcohol containing oxygen-18 and a carboxylic acid in the presence of an acid catalyst (H⁺). Here’s the step-by-step solution: ### Step 1: Identify the Reactants We have two reactants: 1. An alcohol (R-OH) that contains oxygen-18 (denoted as R-^18OH). 2. A carboxylic acid (R'-COOH). ### Step 2: Understand the Reaction Mechanism In the presence of an acid (H⁺), the alcohol can donate a proton (H⁺), and the carboxylic acid can provide a hydroxyl group (OH⁻). This reaction is a typical esterification reaction where an alcohol reacts with a carboxylic acid to form an ester and water. ### Step 3: Formation of the Ester When the alcohol and carboxylic acid react: - The hydroxyl group (OH) from the carboxylic acid and the hydrogen (H) from the alcohol combine to form water (H₂O). - The remaining parts of the alcohol and carboxylic acid combine to form an ester. The general reaction can be represented as: \[ \text{R-}^18\text{OH} + \text{R'-COOH} \xrightarrow{\text{H}^+} \text{R'-COOR} + \text{H}_2\text{O} \] ### Step 4: Identify the Products The product formed is an ester (R'-COOR) where: - R' is the alkyl group from the carboxylic acid. - R is the alkyl group from the alcohol, which contains the oxygen-18. ### Step 5: Conclusion The final products of the reaction are: 1. An ester (R'-COOR) where the oxygen in the ester is the oxygen-18 from the alcohol. 2. Water (H₂O). Thus, the correct product is R'-COOR with the oxygen-18 incorporated into the ester.

To solve the question, we need to analyze the reaction between an alcohol containing oxygen-18 and a carboxylic acid in the presence of an acid catalyst (H⁺). Here’s the step-by-step solution: ### Step 1: Identify the Reactants We have two reactants: 1. An alcohol (R-OH) that contains oxygen-18 (denoted as R-^18OH). 2. A carboxylic acid (R'-COOH). ### Step 2: Understand the Reaction Mechanism ...
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