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R - overset(O)overset(||)(C ) - OH overs...

`R - overset(O)overset(||)(C ) - OH overset([?])(to) R CH_(2) -OH`
Here reagent is

A

`LiAIH_(4)`

B

`NaBH_(4)`

C

Both (1)& (2)

D

Red `P//HI`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of identifying the reagent that converts a carboxylic acid (R-C(=O)-OH) to an alcohol (R-CH2-OH), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction Type**: The reaction involves the conversion of a carboxylic acid (R-C(=O)-OH) to an alcohol (R-CH2-OH). This is a reduction reaction, where the carboxylic acid is being reduced to an alcohol. **Hint**: Recognize that the conversion of a carboxylic acid to an alcohol requires a reducing agent. 2. **List Possible Reagents**: The options given are: - LiAlH4 (Lithium Aluminium Hydride) - NaBH4 (Sodium Borohydride) - Both 1 and 2 - Red P / HI (Red Phosphorus and Hydroiodic Acid) **Hint**: Consider the strength of the reducing agents listed and their typical reactions with carboxylic acids. 3. **Evaluate Each Reagent**: - **LiAlH4**: This is a strong reducing agent capable of reducing carboxylic acids to alcohols. It can donate hydride ions (H-) effectively to the carbonyl carbon of the carboxylic acid. - **NaBH4**: This is a milder reducing agent that primarily reduces aldehydes and ketones. It is not effective for reducing carboxylic acids due to their lower reactivity compared to aldehydes and ketones. - **Both 1 and 2**: Since NaBH4 cannot reduce carboxylic acids, this option is not valid. - **Red P / HI**: This combination can reduce carboxylic acids to alkanes rather than alcohols. Therefore, it is not suitable for this reaction. **Hint**: Compare the reactivity of the reagents with carboxylic acids to determine their suitability. 4. **Conclusion**: Based on the evaluations, the only suitable reagent for the reduction of a carboxylic acid to an alcohol is **LiAlH4**. **Final Answer**: The reagent is **LiAlH4 (Lithium Aluminium Hydride)**.

To solve the question of identifying the reagent that converts a carboxylic acid (R-C(=O)-OH) to an alcohol (R-CH2-OH), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction Type**: The reaction involves the conversion of a carboxylic acid (R-C(=O)-OH) to an alcohol (R-CH2-OH). This is a reduction reaction, where the carboxylic acid is being reduced to an alcohol. **Hint**: Recognize that the conversion of a carboxylic acid to an alcohol requires a reducing agent. ...
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