Statement 1: Primary, secondary and tertiary amines can be separated by Hinsburg reagent and
Statement 2: These amines have different rate of reaction with benzens sulfonyl chloride.

Options

A. Statement-1 is true, Statement-2 is true, statement-2 is a correct explanation for statement-5
B. Statement-1 is true, statement-2 is true, statement-2 is not a correct explanation for statement-5
C. Statement-1 is true, statement-2 is False
D. Statement-1 is False, Statement-2 is True.

Answer

To analyze the statements provided in the question, we will break down the information regarding the separation of amines using Hinsberg reagent and their reactivity with benzene sulfonyl chloride.

### Step-by-Step Solution:

1. **Understanding the Hinsberg Test**:
- The Hinsberg test is a method used to differentiate between primary, secondary, and tertiary amines.
- In this test, an amine reacts with benzene sulfonyl chloride (C6H5SO2Cl) to form sulfonamides.

2. **Reaction of Primary Amines**:
- When a primary amine reacts with benzene sulfonyl chloride, it forms a soluble sulfonamide.
- This soluble product can be separated from the reaction mixture by dissolving it in a suitable solvent.

3. **Reaction of Secondary Amines**:
- Secondary amines also react with benzene sulfonyl chloride, but they typically form a sulfonamide that is less soluble than that from primary amines.
- In many cases, this leads to the formation of a precipitate, which can be separated from the solution.

4. **Reaction of Tertiary Amines**:
- Tertiary amines do not react with benzene sulfonyl chloride in the same way.
- They do not form a soluble sulfonamide and instead lead to the formation of a precipitate as well.

5. **Conclusion on Statement 1**:
- Since primary amines yield soluble products while secondary and tertiary amines yield precipitates, we can conclude that primary, secondary, and tertiary amines can indeed be separated using the Hinsberg reagent.
- Thus, Statement 1 is **True**.

6. **Understanding the Rate of Reaction**:
- The rate of reaction of amines with benzene sulfonyl chloride varies due to the structure of the amines.
- Primary amines have two hydrogen atoms that can be replaced, while secondary amines have one hydrogen atom. Tertiary amines lack hydrogen atoms for replacement.
- This difference in hydrogen availability affects the reactivity and thus the rate of reaction with benzene sulfonyl chloride.

7. **Conclusion on Statement 2**:
- Since primary, secondary, and tertiary amines react at different rates due to their structural differences, Statement 2 is also **True**.

### Final Conclusion:
Both statements are true:
- **Statement 1**: True (Primary, secondary, and tertiary amines can be separated by Hinsberg reagent).
- **Statement 2**: True (These amines have different rates of reaction with benzene sulfonyl chloride).