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In a thermodynamic process on an ideal d...

In a thermodynamic process on an ideal diatomic gas, work done by the gas is `eta` times the heat supplied `(eta lt 1)`. The molar heat capacity of the gas for the process is

A

`(5R)/(2)`

B

`5eta(R)/(2)`

C

`(5R)/(2(1-eta))`

D

`(5R(1-eta))/(2)`

Text Solution

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The correct Answer is:
To find the molar heat capacity of an ideal diatomic gas in a thermodynamic process where the work done by the gas is `eta` times the heat supplied (with `eta < 1`), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the First Law of Thermodynamics**: The first law of thermodynamics states: \[ dQ = dU + dW \] where \(dQ\) is the heat supplied, \(dU\) is the change in internal energy, and \(dW\) is the work done by the gas. 2. **Express Work Done**: According to the problem, the work done by the gas is given by: \[ dW = \eta \cdot dQ \] 3. **Substitute Work Done into the First Law**: Substitute \(dW\) into the first law: \[ dQ = dU + \eta \cdot dQ \] 4. **Rearrange to Find Change in Internal Energy**: Rearranging gives: \[ dU = dQ - \eta \cdot dQ = (1 - \eta) dQ \] 5. **Relate Change in Internal Energy to Temperature Change**: For an ideal gas, the change in internal energy can be expressed as: \[ dU = n C_v dT \] where \(C_v\) is the molar heat capacity at constant volume. 6. **Equate the Two Expressions for Change in Internal Energy**: From the previous steps, we have: \[ n C_v dT = (1 - \eta) dQ \] 7. **Express Heat Supplied**: The heat supplied can be expressed as: \[ dQ = n C dT \] where \(C\) is the molar heat capacity for the process. 8. **Substitute \(dQ\) in the Equation**: Substitute \(dQ\) into the equation: \[ n C_v dT = (1 - \eta) (n C dT) \] 9. **Cancel \(n dT\) from Both Sides**: Assuming \(n \neq 0\) and \(dT \neq 0\), we can cancel \(n dT\): \[ C_v = (1 - \eta) C \] 10. **Solve for Molar Heat Capacity \(C\)**: Rearranging gives: \[ C = \frac{C_v}{1 - \eta} \] 11. **Substitute \(C_v\) for a Diatomic Gas**: For a diatomic ideal gas, the molar heat capacity at constant volume is: \[ C_v = \frac{5}{2} R \] Therefore, \[ C = \frac{\frac{5}{2} R}{1 - \eta} \] ### Final Result: The molar heat capacity \(C\) for the process is: \[ C = \frac{5R}{2(1 - \eta)} \]
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