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An electron in a hydrogen atom makes a t...

An electron in a hydrogen atom makes a transition such that its kinetic energy increases, then

A

The electron may have excited form n=2 to n=3

B

Potential energy of the electron increases

C

Potential energy of the electron decreases

D

Total energy of the electron increases

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the transition of an electron in a hydrogen atom and how it affects its kinetic and potential energy. ### Step-by-Step Solution: 1. **Understanding Kinetic Energy in Hydrogen Atom:** The kinetic energy (KE) of an electron in a hydrogen atom is given by the formula: \[ KE = -\frac{1}{2} \times \text{Total Energy} \] The total energy (E) of the electron in the nth orbit is given by: \[ E = -\frac{13.6 \, \text{eV}}{n^2} \] Therefore, the kinetic energy can be expressed as: \[ KE = -\left(-\frac{13.6 \, \text{eV}}{n^2}\right) \times \frac{1}{2} = \frac{13.6 \, \text{eV}}{2n^2} \] 2. **Effect of Transition on Kinetic Energy:** If the kinetic energy of the electron increases, it implies that the value of \( KE \) is increasing. Since \( KE \) is inversely proportional to \( n^2 \), an increase in kinetic energy means that \( n \) must decrease (i.e., the electron is moving to a lower energy level). 3. **Evaluating the Options:** - **Option A:** Transition from \( n=2 \) to \( n=3 \) - This is incorrect because \( n \) is increasing, which contradicts our finding that \( n \) must decrease for kinetic energy to increase. - **Option B:** Potential energy of the electron increases - This is incorrect. As \( n \) decreases, the potential energy, which is given by: \[ PE = 2 \times E = -\frac{27.2 \, \text{eV}}{n^2} \] also decreases (becomes more negative). - **Option C:** Potential energy of the electron decreases - This is correct. Since \( n \) decreases, the potential energy becomes more negative, indicating a decrease in potential energy. 4. **Conclusion:** The correct answer is that the potential energy of the electron decreases when its kinetic energy increases.
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