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An excited hydrogen atom emits a photon ...

An excited hydrogen atom emits a photon of wavelength `lambda` in returning to the ground state. If 'R' is the Rydberg's constant, then the quantum number 'n' of the excited state is:

A

`sqrt(lambdaR(lambdaR-1))`

B

`sqrt((lambdaR)/(lambdaR-1))`

C

`sqrt((lambdaR-1)/(lambdaR))`

D

`sqrt(1/(lambdaR(lambdaR-1)))`

Text Solution

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The correct Answer is:
To find the quantum number \( n \) of the excited state of a hydrogen atom that emits a photon of wavelength \( \lambda \) while returning to the ground state, we can use the Rydberg formula for hydrogen: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] ### Step-by-Step Solution: 1. **Identify the Ground State Quantum Number**: The ground state of the hydrogen atom corresponds to the quantum number \( n_1 = 1 \). 2. **Substitute \( n_1 \) into the Rydberg Formula**: Substitute \( n_1 = 1 \) into the Rydberg formula: \[ \frac{1}{\lambda} = R \left( \frac{1}{1^2} - \frac{1}{n_2^2} \right) \] This simplifies to: \[ \frac{1}{\lambda} = R \left( 1 - \frac{1}{n_2^2} \right) \] 3. **Rearranging the Equation**: Rearranging the equation gives: \[ \frac{1}{\lambda} = R - \frac{R}{n_2^2} \] Now, isolate the term involving \( n_2 \): \[ \frac{R}{n_2^2} = R - \frac{1}{\lambda} \] 4. **Solve for \( \frac{1}{n_2^2} \)**: Rearranging further gives: \[ \frac{1}{n_2^2} = \frac{R}{R - \frac{1}{\lambda}} \] 5. **Take the Reciprocal**: Taking the reciprocal gives: \[ n_2^2 = \frac{R - \frac{1}{\lambda}}{R} \] 6. **Final Expression for \( n_2 \)**: Therefore, we can express \( n_2 \) as: \[ n_2 = \sqrt{\frac{\lambda R}{\lambda R - 1}} \] ### Conclusion: The quantum number \( n \) of the excited state is given by: \[ n_2 = \sqrt{\frac{\lambda R}{\lambda R - 1}} \]
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