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An electron in a hydrogen atom makes a t...

An electron in a hydrogen atom makes a transition `n_1 to n_2` where `n_1` and `n_2` are principle quantum numbers of the states . Assume the Bohr's model to be valid , the frequency of revolution in initial state is eight times that of final state. The ratio n`n_1/n_2` is

A

`8:1`

B

`4:1`

C

`2:1`

D

`1:2`

Text Solution

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The correct Answer is:
To solve the problem, we need to find the ratio \( \frac{n_1}{n_2} \) given that the frequency of revolution in the initial state \( n_1 \) is eight times that of the final state \( n_2 \). ### Step-by-Step Solution: 1. **Understanding the Frequency Relation**: According to Bohr's model, the frequency of revolution \( f \) of an electron in a hydrogen atom is given by: \[ f \propto \frac{Z^2}{n^3} \] where \( Z \) is the atomic number (which is 1 for hydrogen) and \( n \) is the principal quantum number. 2. **Setting Up the Frequencies**: Let \( f_1 \) be the frequency of revolution in the initial state \( n_1 \) and \( f_2 \) be the frequency in the final state \( n_2 \). According to the problem: \[ f_1 = 8 f_2 \] 3. **Expressing Frequencies in Terms of Quantum Numbers**: From the frequency relation, we can express: \[ f_1 = k \cdot \frac{1}{n_1^3} \quad \text{and} \quad f_2 = k \cdot \frac{1}{n_2^3} \] where \( k \) is a constant. 4. **Substituting the Frequencies**: Substituting the expressions for \( f_1 \) and \( f_2 \) into the equation \( f_1 = 8 f_2 \): \[ k \cdot \frac{1}{n_1^3} = 8 \left( k \cdot \frac{1}{n_2^3} \right) \] 5. **Cancelling the Constant**: Since \( k \) is common on both sides, we can cancel it out: \[ \frac{1}{n_1^3} = 8 \cdot \frac{1}{n_2^3} \] 6. **Rearranging the Equation**: Rearranging gives us: \[ n_2^3 = 8 n_1^3 \] 7. **Taking the Cube Root**: Taking the cube root of both sides: \[ n_2 = 2 n_1 \] 8. **Finding the Ratio**: Therefore, the ratio \( \frac{n_1}{n_2} \) is: \[ \frac{n_1}{n_2} = \frac{n_1}{2 n_1} = \frac{1}{2} \] ### Final Answer: The ratio \( \frac{n_1}{n_2} \) is \( \frac{1}{2} \).
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