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Choose the correct alternatives

A

Ratio to maximum of minimum wavelength obtained in Balmer series of hydrogen spectrum is 1.8

B

For transition of electron from orbit with n=8 to orbit with n=3 , ultraviolet radiations are emitted

C

Lyman series corresponds to ultraviolet region of radiation

D

Spectrum of hydrogen is continuous

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to evaluate each option provided regarding the hydrogen spectrum and determine which ones are correct. ### Step-by-Step Solution: **Option A: The ratio of maximum to minimum wavelength obtained in the Balmer series of hydrogen spectrum is 1.8.** 1. The formula for the wavelength in the Balmer series is given by: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{2^2} - \frac{1}{n^2} \right) \] where \( R_H \) is the Rydberg constant, and \( n \) can take values 3, 4, 5, etc. 2. Calculate the minimum wavelength when \( n \) approaches infinity: \[ \frac{1}{\lambda_1} = R_H \left( \frac{1}{2^2} - 0 \right) = \frac{R_H}{4} \] Thus, \( \lambda_1 = \frac{4}{R_H} \). 3. Calculate the maximum wavelength when \( n = 3 \): \[ \frac{1}{\lambda_2} = R_H \left( \frac{1}{2^2} - \frac{1}{3^2} \right) = R_H \left( \frac{1}{4} - \frac{1}{9} \right) = R_H \left( \frac{9 - 4}{36} \right) = \frac{5R_H}{36} \] Thus, \( \lambda_2 = \frac{36}{5R_H} \). 4. Now, find the ratio of maximum to minimum wavelengths: \[ \frac{\lambda_{\text{max}}}{\lambda_{\text{min}}} = \frac{\lambda_2}{\lambda_1} = \frac{\frac{36}{5R_H}}{\frac{4}{R_H}} = \frac{36}{5} \cdot \frac{R_H}{4} = \frac{36}{20} = 1.8 \] **Conclusion for Option A:** This option is correct. --- **Option B: For the transition of an electron from orbit with \( n = 8 \) to orbit with \( n = 3 \), ultraviolet radiation is emitted.** 1. The transition from a higher energy level to a lower one emits radiation. The formula for wavelength is: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{3^2} - \frac{1}{8^2} \right) \] Calculate: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{9} - \frac{1}{64} \right) = R_H \left( \frac{64 - 9}{576} \right) = \frac{55R_H}{576} \] 2. The wavelength \( \lambda \) can be calculated as: \[ \lambda = \frac{576}{55R_H} \] Given that \( R_H \approx 911 \) Å, we can find \( \lambda \): \[ \lambda \approx \frac{576 \times 911}{55} \approx 9540 \text{ Å} \] This wavelength is in the infrared region, not ultraviolet. **Conclusion for Option B:** This option is incorrect. --- **Option C: Lyman series corresponds to the ultraviolet region of radiation.** 1. The Lyman series involves transitions to \( n = 1 \) from higher levels (n = 2, 3, ...). All wavelengths in the Lyman series fall within the ultraviolet region. **Conclusion for Option C:** This option is correct. --- **Option D: The spectrum of hydrogen is continuous.** 1. The spectrum of hydrogen is not continuous; it consists of discrete lines corresponding to specific transitions between energy levels. **Conclusion for Option D:** This option is incorrect. --- ### Final Answers: - **Correct Options:** A, C - **Incorrect Options:** B, D
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