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When an electron revolving in the ground...

When an electron revolving in the ground state of a hydrogen atom jumps to its `2^"nd"` excited state.

A

It frequency of revolution becomes `(3)^(2//3)` times

B

It frequency of revolution becomes `(3)^(-3)` times

C

Its speed becomes `(1/3)` times

D

Its speed becomes `(1/9)` times

Text Solution

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The correct Answer is:
To solve the problem of an electron in a hydrogen atom jumping from the ground state to its second excited state, we will follow these steps: ### Step 1: Identify the Initial and Final States The ground state of a hydrogen atom corresponds to the principal quantum number \( n_1 = 1 \). The second excited state corresponds to \( n_2 = 3 \) (since the first excited state is \( n = 2 \)). ### Step 2: Understand the Relationship Between Frequency and Principal Quantum Number The frequency of revolution of an electron in a hydrogen atom is inversely proportional to the cube of the principal quantum number. This can be expressed mathematically as: \[ f \propto \frac{1}{n^3} \] Thus, we can write the ratio of the frequencies for the two states as: \[ \frac{f_1}{f_2} = \frac{n_2^3}{n_1^3} \] ### Step 3: Calculate the Frequencies Substituting the values of \( n_1 \) and \( n_2 \): \[ \frac{f_1}{f_2} = \frac{3^3}{1^3} = \frac{27}{1} = 27 \] This implies: \[ f_2 = \frac{f_1}{27} \] ### Step 4: Analyze the Speed of the Electron The speed of the electron is inversely proportional to the principal quantum number: \[ v \propto \frac{1}{n} \] Thus, the ratio of the speeds can be expressed as: \[ \frac{v_1}{v_2} = \frac{n_2}{n_1} \] Substituting the values: \[ \frac{v_1}{v_2} = \frac{3}{1} = 3 \] This implies: \[ v_2 = \frac{v_1}{3} \] ### Step 5: Conclusion From the calculations: - The frequency of revolution in the second excited state becomes \( \frac{1}{27} \) times that in the ground state. - The speed of the electron in the second excited state becomes \( \frac{1}{3} \) times that in the ground state. Thus, the correct options based on the question are: - The frequency of revolution becomes \( \frac{1}{27} \) times. - The speed becomes \( \frac{1}{3} \) times.
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