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(CH(3))(2)COoverset(NaCN)underset(HCI)ra...

`(CH_(3))_(2)COoverset(NaCN)underset(HCI)rarr(A)underset(Delta)overset(H_(3)^(+)O)rarr(B)`
In the above sequence of reactions, (A) and (B) are :

A

`(CH_(3))_(2)C(OH)CN. (CH_(3))_(2)C(OH)COOH`

B

`(CH_(3))_(2)C(OH)CNH_(2). (CH_(3))_(2)C(OH)_(2)`

C

`(CH_(3))_(2)C(OH)CN.(CH_(3))_(2)CHCOOH`

D

`(CH_(3))_(2)C(OH)CNH_(2).(CH_(3))_(2)C=0`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we will analyze the reaction step by step. ### Step 1: Identify the starting compound The starting compound is (CH₃)₂CO, which is acetone (a ketone). The structure of acetone is: ``` O || CH₃-C-CH₃ ``` ### Step 2: Nucleophilic attack by CN⁻ In the presence of NaCN, the cyanide ion (CN⁻) acts as a nucleophile. The carbonyl carbon of acetone is electrophilic due to the partial positive charge on it. The CN⁻ ion attacks the carbonyl carbon, leading to the formation of a cyanohydrin. The reaction can be represented as follows: ``` (CH₃)₂CO + CN⁻ → (CH₃)₂C(OH)(CN) ``` This product can be denoted as A: ``` A: (CH₃)₂C(OH)(CN) ``` ### Step 3: Protonation of the alkoxide When the product A reacts with HCl, the alkoxide (O⁻) gets protonated: ``` (CH₃)₂C(OH)(CN) + H⁺ → (CH₃)₂C(OH)(CN) ``` This step does not change the structure of A but confirms that we have a hydroxyl group and a cyanide group attached to the same carbon. ### Step 4: Hydrolysis of the cyanide group Now, when product A undergoes hydrolysis in the presence of heat (Δ), the CN group is converted into a carboxylic acid (COOH). This reaction can be represented as: ``` (CH₃)₂C(OH)(CN) + H₂O → (CH₃)₂C(OH)(COOH) ``` This product can be denoted as B: ``` B: (CH₃)₂C(COOH)(OH) ``` ### Final Products Thus, the final products are: - (A) = (CH₃)₂C(OH)(CN) - (B) = (CH₃)₂C(COOH)(OH) ### Summary of Products - A: (CH₃)₂C(OH)(CN) - B: (CH₃)₂C(COOH)(OH)
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AAKASH INSTITUTE ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -Assignment (Section A Competition Level Questions)
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  2. An alkene of molecular formula C(9) H(18) on ozonolysis gives 2.2 dime...

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  3. (CH(3))(2)COoverset(NaCN)underset(HCI)rarr(A)underset(Delta)overset(H(...

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  4. A liquid was mixed with ethanol and a drop of concentrated H(2) SO(4) ...

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  5. The major product obtained on interaction of phenol with sodium hydrox...

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  6. Which of the following does not give benzoic acid on hydrolysis?

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  7. The compound x is

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  8. Acetic acid is obtained when

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  9. When m-chlorobenzaldehyde is treated with 50% KOH solution, the produc...

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  10. Aldol condensation will not be observed in

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  11. Whch of the following gives aldol condensation reaction?

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  12. Which of the following organic compound exhibits positive Fehling test...

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  13. Predict the product

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  14. Which of the following will not undergo aldol condensation-

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  15. Benzyl alcohol and sodium benzoate is obtained by the action of sodium...

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  16. Dimethyl ketones are usually characterised through

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  17. In the Cannizzaro reaction given below: 2Ph-CHO overset(overset(Θ)OH...

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  18. Trichloroacetaldehyde, C Cl(3)CHO reacts with chlorobenzene in presenc...

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  19. The order of reactivity of CH(3)CHO, CH(3)COC(2)H(5) and CH(3)COCH(3) ...

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