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Whch of the following gives aldol conden...

Whch of the following gives aldol condensation reaction?

A

`C_(6)H_(5)OH`

B

`C_(6)H_(5)overset(O)overset(||)C-C_(6)H_(5)`

C

`CH_(3)CH_(2)-underset(O)underset(||)O-CH_(3)`

D

`(CH_(3))_(3)C-underset(O)underset(||)C-C(CH_(3))_(3)`

Text Solution

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The correct Answer is:
To determine which of the given compounds undergoes aldol condensation, we need to follow these steps: ### Step 1: Understand Aldol Condensation Aldol condensation is a reaction between two carbonyl compounds where one compound forms an enolate ion, which then reacts with another carbonyl compound in the presence of a base (like NaOH) to form a β-hydroxy carbonyl compound. This can further dehydrate to yield an α,β-unsaturated carbonyl compound (conjugated enone). ### Step 2: Identify the Requirement for Aldol Condensation For a compound to undergo aldol condensation, it must have: - A carbonyl group (aldehyde or ketone). - At least one alpha hydrogen (hydrogens attached to the carbon adjacent to the carbonyl carbon). ### Step 3: Analyze Each Compound Now, let's analyze the given compounds to check for the presence of alpha hydrogens: 1. **Compound 1**: If it is a ketone or aldehyde with no alpha hydrogens, it cannot undergo aldol condensation. 2. **Compound 2**: If it has a carbonyl group and at least one alpha hydrogen, it can undergo aldol condensation. 3. **Compound 3**: Similar to the first, if it lacks alpha hydrogens, it cannot undergo the reaction. ### Step 4: Conclude After analyzing: - Identify which compound has the alpha hydrogen. - The compound that has alpha hydrogens will be the one that can undergo aldol condensation. ### Example Conclusion If we find that Compound 2 has alpha hydrogens while the others do not, we conclude that **Compound 2** is the one that gives aldol condensation reaction.
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AAKASH INSTITUTE ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -Assignment (Section A Competition Level Questions)
  1. When m-chlorobenzaldehyde is treated with 50% KOH solution, the produc...

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  2. Aldol condensation will not be observed in

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  3. Whch of the following gives aldol condensation reaction?

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  4. Which of the following organic compound exhibits positive Fehling test...

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  5. Predict the product

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  6. Which of the following will not undergo aldol condensation-

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  7. Benzyl alcohol and sodium benzoate is obtained by the action of sodium...

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  8. Dimethyl ketones are usually characterised through

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  9. In the Cannizzaro reaction given below: 2Ph-CHO overset(overset(Θ)OH...

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  10. Trichloroacetaldehyde, C Cl(3)CHO reacts with chlorobenzene in presenc...

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  11. The order of reactivity of CH(3)CHO, CH(3)COC(2)H(5) and CH(3)COCH(3) ...

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  14. Select the reagent for the following reaction:

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  15. An organic compound (X) with molecular formula C(9)H(10)O gives positi...

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  16. The increasing order of the rate of HCN addition to compound A-D is ...

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  17. The correct order of reactivity of PhMgBr with underset((I))(Ph-unde...

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  18. Identify 'X'

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  19. The diketone CH(3)-overset(overset(O)(||))(C)-(CH(2))(2)-overset(over...

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  20. What will be the product , when carboxy phenol, obtained by Reimer Tie...

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