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An organic compound (X) with molecular f...

An organic compound (X) with molecular formula `C_(9)H_(10)O` gives positive 2, 4-DNP and Tollens'tests. It undergoes Cannizzaro reaction and on vigorous oxidation it gives 1, 4-benzenedicarboxylic acid. Compound (X) is

A

B

C

D

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The correct Answer is:
A
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(a) Give a possible explaination for each one of the following : - (i) There are two - NH_(2) groups in semicarbazide. However, only one such group is involvedin the formation of semicarbazones. (ii) Cyclohexanone forms cyanohydrin in good yield but 2,4,6 -trimethylcyclohexanone does not. (b) An organic compound with molecular formula C_(9)H_(10)O forms, 2,4 - DNP derivative, reduces Tollens' reagent and undergoes Cannizzaro reaction. On vigorous oxidation it gives 1,2-benzene-di-carboxylic acid. Identify the compound.

AAKASH INSTITUTE ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -Assignment (Section A Competition Level Questions)

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  2. Select the reagent for the following reaction:

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  3. An organic compound (X) with molecular formula C(9)H(10)O gives positi...

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  4. The increasing order of the rate of HCN addition to compound A-D is ...

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  5. The correct order of reactivity of PhMgBr with underset((I))(Ph-unde...

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  6. Identify 'X'

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  7. The diketone CH(3)-overset(overset(O)(||))(C)-(CH(2))(2)-overset(over...

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  8. What will be the product , when carboxy phenol, obtained by Reimer Tie...

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  9. Which of the following aromatic acids is most acidic?

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  10. CH(3)COOH overset (Delta) underset (P(2)O(5)) to X. Identify X

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  11. Which one of the following orders of acidic strength is correct?

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  12. Which of the following represents the correct order of acidity in the ...

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  13. The correct order of acidic strength is

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  14. Treatment of benzoic acid with Cl(2)//FeCl(3) will give

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  15. In esterfication

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  16. Acetyl chloride is reduced with LiAlH(4) , the product formed is

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  17. The reaction CH(3) COOH + Cl(2) overset (red P) to CICH(2) COOH + HC...

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  18. Saponification of ethyl benzoate with caustic soda as alkali gives

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  19. Which of the following acids has the smallest dissociation constant?

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  20. Which of the following compounds will show the maximum ‘enol’ content?

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