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A sample of gas in a box is at pressure ...

A sample of gas in a box is at pressure `P_0` and temperature `T_0`. If number of molecules is doubled and total kinetic energy of the gas is kept constant, then final temperature and pressure will be

A

`T_0 . P_0`

B

`T_0, 2P_0`

C

`(T_0)/(2), 2P_0`

D

`(T_0)/(2), P_0`

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The correct Answer is:
To solve the problem, we need to analyze the relationship between the number of molecules, temperature, and pressure of the gas, given that the total kinetic energy remains constant. ### Step-by-Step Solution: 1. **Understanding Kinetic Energy**: The total average kinetic energy (KE) of a gas is given by the formula: \[ KE = \frac{F}{2} n k T \] where \( F \) is the degrees of freedom, \( n \) is the number of molecules, \( k \) is the Boltzmann constant, and \( T \) is the temperature. 2. **Initial Conditions**: For the initial state of the gas, we have: \[ KE_0 = \frac{F}{2} n_0 k T_0 \] where \( n_0 \) is the initial number of molecules and \( T_0 \) is the initial temperature. 3. **Final Conditions**: The problem states that the number of molecules is doubled, so: \[ n_f = 2n_0 \] Let the final temperature be \( T_f \). The total kinetic energy remains constant, so: \[ KE_f = \frac{F}{2} n_f k T_f = \frac{F}{2} (2n_0) k T_f = F n_0 k T_f \] 4. **Setting Initial and Final Kinetic Energies Equal**: Since the total kinetic energy is constant: \[ KE_0 = KE_f \] Therefore: \[ \frac{F}{2} n_0 k T_0 = F n_0 k T_f \] 5. **Simplifying the Equation**: We can cancel \( F \), \( n_0 \), and \( k \) from both sides (assuming they are not zero): \[ \frac{1}{2} T_0 = T_f \] Thus, the final temperature is: \[ T_f = \frac{T_0}{2} \] 6. **Finding Final Pressure**: Using the ideal gas law \( PV = nRT \), we can express pressure as: \[ P = \frac{nRT}{V} \] Since the volume \( V \) is constant and the gas is the same, we can express it in terms of the Boltzmann constant: \[ P = \frac{n k T}{V} \] Initially, we have: \[ P_0 = \frac{n_0 k T_0}{V} \] For the final state: \[ P_f = \frac{(2n_0) k T_f}{V} = \frac{(2n_0) k \left(\frac{T_0}{2}\right)}{V} = \frac{n_0 k T_0}{V} = P_0 \] Therefore, the final pressure remains: \[ P_f = P_0 \] ### Final Results: - Final Temperature \( T_f = \frac{T_0}{2} \) - Final Pressure \( P_f = P_0 \)
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