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A given sample of an ideal gas occupise ...

A given sample of an ideal gas occupise a volume V at a pressure p and absolute temperature T.The mass of each molecule of the gas is m. Which of the following is the density of the gas ?

A

`(P)/((kT))`

B

`(Pm)/((kT))`

C

`(P)/((kTV))`

D

`mkT`

Text Solution

AI Generated Solution

The correct Answer is:
To find the density of the gas given the conditions in the problem, we can follow these steps: ### Step 1: Understand the Ideal Gas Law The ideal gas law is given by the equation: \[ PV = nRT \] where: - \( P \) = pressure, - \( V \) = volume, - \( n \) = number of moles, - \( R \) = universal gas constant, - \( T \) = absolute temperature. ### Step 2: Relate Moles to Mass The number of moles \( n \) can be expressed in terms of mass \( m \) and molar mass \( M \): \[ n = \frac{m}{M} \] where \( m \) is the total mass of the gas and \( M \) is the molar mass. ### Step 3: Substitute for Moles in the Ideal Gas Law Substituting \( n \) into the ideal gas law gives: \[ PV = \frac{m}{M} RT \] ### Step 4: Rearranging for Density Density \( \rho \) is defined as mass per unit volume: \[ \rho = \frac{m}{V} \] From the equation \( PV = \frac{m}{M} RT \), we can rearrange it to express \( m \) in terms of \( P \), \( V \), and \( T \): \[ m = \frac{PVM}{RT} \] ### Step 5: Substitute Mass into the Density Equation Now substituting \( m \) back into the density equation: \[ \rho = \frac{m}{V} = \frac{PVM}{RTV} \] This simplifies to: \[ \rho = \frac{PM}{RT} \] ### Step 6: Relate Molar Mass to Molecular Mass Since \( M \) (molar mass) can be expressed in terms of the mass of a single molecule \( m \) and Avogadro's number \( N_A \): \[ M = m \cdot N_A \] Substituting this into the density equation gives: \[ \rho = \frac{P(m \cdot N_A)}{RT} \] ### Step 7: Use Boltzmann's Constant We know that the universal gas constant \( R \) can be related to Boltzmann's constant \( k_B \): \[ R = N_A k_B \] Substituting \( R \) into the density equation: \[ \rho = \frac{P(m \cdot N_A)}{N_A k_B T} \] This simplifies to: \[ \rho = \frac{Pm}{k_B T} \] ### Final Result Thus, the density of the gas is given by: \[ \rho = \frac{Pm}{k_B T} \]
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