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A hydrogen atom is in ground state. In o...

A hydrogen atom is in ground state. In order to get six lines in its emission spectrum, wavelength of incident radiation should be

A

800 A

B

825 A

C

970 A

D

1025 A

Text Solution

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To solve the problem of finding the wavelength of incident radiation required to get six lines in the emission spectrum of a hydrogen atom in the ground state, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Emission Spectrum**: The number of spectral lines emitted when an electron transitions from a higher energy level (n) to the ground state (n=1) can be calculated using the formula: \[ \text{Number of lines} = \frac{n(n-1)}{2} \] 2. **Setting Up the Equation**: Given that we want 6 spectral lines, we can set up the equation: \[ 6 = \frac{n(n-1)}{2} \] 3. **Solving for n**: To find n, we can rearrange the equation: \[ 12 = n(n-1) \] This simplifies to: \[ n^2 - n - 12 = 0 \] We can factor this quadratic equation: \[ (n - 4)(n + 3) = 0 \] Thus, \( n = 4 \) (since n cannot be negative). 4. **Finding the Wavelength**: Now, we need to find the wavelength of the radiation corresponding to the transition from n=4 to n=1. We use the Rydberg formula: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R \) is the Rydberg constant (approximately \( 1.097 \times 10^7 \, \text{m}^{-1} \)), \( n_1 = 1 \), and \( n_2 = 4 \). 5. **Substituting Values**: Substituting the values into the formula: \[ \frac{1}{\lambda} = R \left( \frac{1}{1^2} - \frac{1}{4^2} \right) = R \left( 1 - \frac{1}{16} \right) = R \left( \frac{16 - 1}{16} \right) = R \left( \frac{15}{16} \right) \] 6. **Calculating λ**: Thus, \[ \frac{1}{\lambda} = R \cdot \frac{15}{16} \] Therefore, \[ \lambda = \frac{16}{15R} \] 7. **Substituting Rydberg Constant**: Now, substituting \( R \): \[ \lambda = \frac{16}{15 \cdot 1.097 \times 10^7} \approx 970 \, \text{Å} \] ### Final Answer: The wavelength of the incident radiation required to get six lines in the emission spectrum of a hydrogen atom in the ground state is approximately **970 Å**. ---
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