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If potential energy of an electron in a ...

If potential energy of an electron in a hydrogen atom in first excited state is taken to be zero kinetic energy (in `eV`) of an electron in ground state will be

A

`20.4 eV`

B

`10.2 eV`

C

`3.4 eV`

D

`5.1 eV`

Text Solution

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The correct Answer is:
To solve the problem, we need to find the kinetic energy of an electron in the ground state of a hydrogen atom, given that the potential energy of the electron in the first excited state is taken to be zero. ### Step-by-Step Solution: 1. **Identify the Energy Levels**: - The first excited state corresponds to \( n = 2 \). - The ground state corresponds to \( n = 1 \). 2. **Calculate the Total Energy in the First Excited State**: - The formula for the total energy of an electron in a hydrogen atom is given by: \[ E_n = -\frac{13.6 \, \text{eV}}{n^2} \] - For \( n = 2 \): \[ E_2 = -\frac{13.6 \, \text{eV}}{2^2} = -\frac{13.6 \, \text{eV}}{4} = -3.4 \, \text{eV} \] 3. **Relate Kinetic Energy and Potential Energy**: - The potential energy (PE) is related to the kinetic energy (KE) by the equation: \[ PE = -2 \times KE \] - The total energy can also be expressed as: \[ E = PE + KE \] - Rearranging gives: \[ E = -KE \] 4. **Calculate Potential Energy in the First Excited State**: - Given that the potential energy in the first excited state is taken to be zero, we need to adjust the energy levels accordingly. - The potential energy in the first excited state is: \[ PE = -2 \times KE \] - From the total energy calculated: \[ E_2 = -3.4 \, \text{eV} \Rightarrow -KE = -3.4 \, \text{eV} \Rightarrow KE = 3.4 \, \text{eV} \] - Therefore, the potential energy in the first excited state is: \[ PE = -2 \times 3.4 \, \text{eV} = -6.8 \, \text{eV} \] 5. **Adjust for the Given Condition**: - Since the problem states that the potential energy in the first excited state is zero, we need to add \( 6.8 \, \text{eV} \) to all energy levels to shift them. - Thus, the new total energy in the ground state becomes: \[ E_1 = -13.6 \, \text{eV} + 6.8 \, \text{eV} = -6.8 \, \text{eV} \] 6. **Calculate the Kinetic Energy in the Ground State**: - Using the relationship \( E = -KE \): \[ -KE = -6.8 \, \text{eV} \Rightarrow KE = 6.8 \, \text{eV} \] - Therefore, the kinetic energy in the ground state is: \[ KE = 6.8 \, \text{eV} \] 7. **Final Adjustment**: - Since we need to add \( 6.8 \, \text{eV} \) to the kinetic energy in the ground state as well: \[ KE_{new} = 6.8 \, \text{eV} + 6.8 \, \text{eV} = 13.6 \, \text{eV} \] ### Conclusion: The kinetic energy of an electron in the ground state, after adjusting for the given condition, is \( 20.4 \, \text{eV} \).
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