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An electron makes a transition from orbi...

An electron makes a transition from orbit `n = 4` to the orbit `n = 2` of a hydrogen atom. The wave length of the emitted radiations `(R =` Rydberg's constant) will be

A

`16/(4R)`

B

`16/(5R)`

C

`16/(2R)`

D

`16/(3R)`

Text Solution

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The correct Answer is:
To find the wavelength of the emitted radiation when an electron transitions from orbit \( n = 4 \) to orbit \( n = 2 \) in a hydrogen atom, we can use the Rydberg formula for hydrogen spectral lines: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right) \] Where: - \( \lambda \) is the wavelength of the emitted radiation, - \( R \) is the Rydberg constant, - \( n_f \) is the final energy level, - \( n_i \) is the initial energy level. ### Step 1: Identify the values of \( n_f \) and \( n_i \) From the problem statement: - The initial state \( n_i = 4 \) - The final state \( n_f = 2 \) ### Step 2: Substitute the values into the Rydberg formula Substituting \( n_f \) and \( n_i \) into the formula gives: \[ \frac{1}{\lambda} = R \left( \frac{1}{2^2} - \frac{1}{4^2} \right) \] ### Step 3: Calculate \( \frac{1}{n_f^2} \) and \( \frac{1}{n_i^2} \) Calculating \( \frac{1}{n_f^2} \) and \( \frac{1}{n_i^2} \): \[ \frac{1}{n_f^2} = \frac{1}{2^2} = \frac{1}{4} \] \[ \frac{1}{n_i^2} = \frac{1}{4^2} = \frac{1}{16} \] ### Step 4: Substitute these values back into the equation Now substituting these values back into the equation: \[ \frac{1}{\lambda} = R \left( \frac{1}{4} - \frac{1}{16} \right) \] ### Step 5: Find a common denominator and simplify To simplify \( \frac{1}{4} - \frac{1}{16} \), we need a common denominator: \[ \frac{1}{4} = \frac{4}{16} \] So, \[ \frac{1}{4} - \frac{1}{16} = \frac{4}{16} - \frac{1}{16} = \frac{3}{16} \] ### Step 6: Substitute back into the equation Now substituting this back into the equation: \[ \frac{1}{\lambda} = R \cdot \frac{3}{16} \] ### Step 7: Take the reciprocal to find \( \lambda \) Taking the reciprocal gives: \[ \lambda = \frac{16}{3R} \] ### Final Result Thus, the wavelength of the emitted radiation when the electron transitions from \( n = 4 \) to \( n = 2 \) is: \[ \lambda = \frac{16}{3R} \]
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