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Half life of a first order chemical reac...

Half life of a first order chemical reaction is 69 hr at 300 K. Also , rate of this reaction is doubled as temperature is increased from 300 K to 310 K. Determine activation energy and pre - exponential factor for this reaction.

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To solve the problem step-by-step, we will follow the necessary calculations to determine the activation energy (Ea) and the pre-exponential factor (A) for the given first-order reaction. ### Step 1: Determine the rate constant (k1) at 300 K The half-life (t1/2) of a first-order reaction is given by the formula: \[ t_{1/2} = \frac{0.693}{k} ...
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AAKASH INSTITUTE ENGLISH-CHEMICAL KINETICS-ASSIGNMENT (SECTION D : Assertion - Reason Type Questions)
  1. Half life of a first order chemical reaction is 69 hr at 300 K. Also ,...

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  2. A : Rate of reaction depends upon the concentration of the reactants. ...

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  3. A : NO2+COoverset("Slow")rarrCO2+NO Rate =K[NO2]^2 R : Rate does n...

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  4. A : If temperature does not affect the rate of reaction , Ea=0 R : L...

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  5. A : The rate constant of first order reaction is used to calculate pop...

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  6. A : A positive catalyst increases the rate of reaction . R : A posit...

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  7. A : The molecularity of reaction can never be fractional. R : Molecu...

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  8. A : The decomposition of gaseous N2O5 follows first order kinetics. ...

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  9. Assertion : Complex reaction takes place in different steps and the sl...

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  10. A : Rate constant increases with temperature. R : Rate of exothermic...

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  11. A : Hydrolysis of ester in acidic medium follows first order kinetics....

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  12. A : The rate constant of zero order reaction is equal to rate of react...

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  13. A : For exothermic reaction, DeltaH=Ea (forward) -Ea (backward) R ...

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  14. A : Arrhenius parameter (A) = P (steric factor) xx z (collision freq...

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  15. A : In presence of +ve catalyst, activation energy & threshold energy ...

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  16. A : when temperature becomes oo then the value of rate constant is max...

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