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For the first order reaction, the taken ...

For the first order reaction, the taken to reduce the initial concentration to a factor of `1/4` is 10 minutes if the reduction in concentration is carried out to a factor of `1/16`, then time required will be

A

10 minutes

B

20 minutes

C

40 minutes

D

60 minutes

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The correct Answer is:
To solve the problem, we need to understand the concept of half-lives in the context of first-order reactions. ### Step-by-Step Solution: 1. **Understanding the Problem:** We are given that for a first-order reaction, the time taken to reduce the initial concentration to a factor of \( \frac{1}{4} \) is 10 minutes. We need to find the time required to reduce the concentration to a factor of \( \frac{1}{16} \). 2. **Relating Concentration Reductions to Half-Lives:** - Reducing the concentration to \( \frac{1}{4} \) means that the concentration has gone through 2 half-lives. This is because: \[ \frac{A_0}{2} \to \frac{A_0}{4} \quad \text{(2 half-lives)} \] - Since it takes 10 minutes to reduce the concentration to \( \frac{1}{4} \), this means: \[ \text{Time for 2 half-lives} = 10 \text{ minutes} \] 3. **Calculating the Time for 1 Half-Life:** - From the above, we can find the time for one half-life (\( t_{1/2} \)): \[ t_{1/2} = \frac{10 \text{ minutes}}{2} = 5 \text{ minutes} \] 4. **Finding Time for Reduction to \( \frac{1}{16} \):** - Reducing the concentration to \( \frac{1}{16} \) means that the concentration has gone through 4 half-lives: \[ \frac{A_0}{2} \to \frac{A_0}{4} \to \frac{A_0}{8} \to \frac{A_0}{16} \quad \text{(4 half-lives)} \] - Therefore, the time required for 4 half-lives is: \[ \text{Time for 4 half-lives} = 4 \times t_{1/2} = 4 \times 5 \text{ minutes} = 20 \text{ minutes} \] 5. **Final Calculation:** - Thus, the time required to reduce the concentration to a factor of \( \frac{1}{16} \) is: \[ \text{Time} = 4 \times 5 \text{ minutes} = 20 \text{ minutes} \] ### Conclusion: The time required to reduce the concentration to a factor of \( \frac{1}{16} \) is **20 minutes**.
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