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Two moles of a gas at temperature T and ...

Two moles of a gas at temperature T and volume V are heated to twice its volume at constant pressure. If `(C _(p))/(C _(v)) = gamma` then increase in internal energy of the gas is-

A

`(RT)/(gamma - 1)`

B

`(2 RT)/( gamma - 1)`

C

`(2 RT)/( 3( gamma - 1))`

D

`(2T)/( gamma - 1)`

Text Solution

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The correct Answer is:
To find the increase in internal energy of the gas when it is heated at constant pressure, we can follow these steps: ### Step 1: Understand the relationship between internal energy, temperature, and heat capacities. The change in internal energy (\( \Delta U \)) for an ideal gas can be expressed as: \[ \Delta U = n C_v \Delta T \] where \( n \) is the number of moles, \( C_v \) is the molar heat capacity at constant volume, and \( \Delta T \) is the change in temperature. ### Step 2: Determine the change in temperature (\( \Delta T \)). Since the gas is heated at constant pressure and its volume is doubled, we can use the ideal gas law: \[ PV = nRT \] Given that the pressure is constant, if the volume doubles, the temperature must also double. Therefore, if the initial temperature is \( T \), the final temperature \( T_f \) will be: \[ T_f = 2T \] Thus, the change in temperature is: \[ \Delta T = T_f - T = 2T - T = T \] ### Step 3: Relate \( C_v \) to \( C_p \) using the given ratio \( \frac{C_p}{C_v} = \gamma \). From the relationship between heat capacities: \[ C_p = \gamma C_v \] We can also use the relation: \[ C_p - C_v = R \] Substituting \( C_p \): \[ \gamma C_v - C_v = R \] This simplifies to: \[ C_v(\gamma - 1) = R \] Thus, we can express \( C_v \): \[ C_v = \frac{R}{\gamma - 1} \] ### Step 4: Substitute \( C_v \) and \( \Delta T \) into the equation for \( \Delta U \). Now substituting \( C_v \) and \( \Delta T \) into the equation for internal energy: \[ \Delta U = n C_v \Delta T = 2 \left(\frac{R}{\gamma - 1}\right) T \] This gives us: \[ \Delta U = \frac{2RT}{\gamma - 1} \] ### Final Answer: The increase in internal energy of the gas is: \[ \Delta U = \frac{2RT}{\gamma - 1} \]
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