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A: 50 ml, decinormal HCl when mixed with...

A: 50 ml, decinormal HCl when mixed with 50 ml, decinormal `H_(2) SO_(4)`, then normality of `H^(+)` ion in resultant solution is 0.1 N.
R: Here, `MV = M_(1)V_(1) - M_(2)V_(2)`

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion

C

If Assertion is true statement but Reason is false

D

If both Assertion and Reason are false statements

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the normality of \( H^+ \) ions in the resultant solution when 50 mL of decinormal \( HCl \) is mixed with 50 mL of decinormal \( H_2SO_4 \). ### Step 1: Understand the given concentrations - \( HCl \) is decinormal, which means its normality \( N_1 = 0.1 \, N \). - \( H_2SO_4 \) is also decinormal, so its normality \( N_2 = 0.1 \, N \). ### Step 2: Determine the volumes of the solutions - Volume of \( HCl \) solution, \( V_1 = 50 \, mL \). - Volume of \( H_2SO_4 \) solution, \( V_2 = 50 \, mL \). ### Step 3: Calculate the total volume of the mixed solution - Total volume \( V_f = V_1 + V_2 = 50 \, mL + 50 \, mL = 100 \, mL \). ### Step 4: Calculate the total equivalents of \( H^+ \) ions from both acids - For \( HCl \), it releases 1 equivalent of \( H^+ \) per mole, so: \[ \text{Equivalents from } HCl = N_1 \times V_1 = 0.1 \, N \times 50 \, mL = 5 \, equivalents \] - For \( H_2SO_4 \), it releases 2 equivalents of \( H^+ \) per mole, so: \[ \text{Equivalents from } H_2SO_4 = N_2 \times V_2 \times 2 = 0.1 \, N \times 50 \, mL \times 2 = 10 \, equivalents \] ### Step 5: Calculate the total equivalents of \( H^+ \) ions in the resultant solution - Total equivalents of \( H^+ \) ions: \[ \text{Total } H^+ = 5 + 10 = 15 \, equivalents \] ### Step 6: Calculate the normality of \( H^+ \) ions in the resultant solution - Normality of \( H^+ \) ions in the final solution: \[ N_f = \frac{\text{Total equivalents of } H^+}{\text{Total volume in L}} = \frac{15 \, equivalents}{0.1 \, L} = 0.15 \, N \] ### Step 7: Conclusion The assertion states that the normality of \( H^+ \) ions in the resultant solution is \( 0.1 \, N \), which is incorrect based on our calculations. Therefore, the assertion is false.
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