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A : The radius of second orbit of h...

A : The radius of second orbit of ` he^(+)` is equal to that of first orbit of hydrogen
R : The radius of an orbit in hydrogen like species is directly proportional to n and inversely proportional to Z .

A

IF both assertion & reason are true and the reason is the correct explanation of the assertion then mark

B

IF both assertion & reason are true but the reason is not the correct explanation of the assertion , then mark

C

IF assertion is true statement but reason is false , then mark

D

If both assertion and reason are false statements then mark

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze both the assertion (A) and the reason (R) step by step. ### Step 1: Understanding the Assertion (A) The assertion states that the radius of the second orbit of \( \text{He}^+ \) is equal to that of the first orbit of hydrogen. ### Step 2: Calculate the Radius of the Second Orbit of \( \text{He}^+ \) According to Bohr's model, the radius of the nth orbit is given by the formula: \[ R_n = \frac{0.53 \, n^2}{Z} \, \text{Å} \] For \( \text{He}^+ \): - \( n = 2 \) (second orbit) - \( Z = 2 \) (atomic number of helium) Substituting these values into the formula: \[ R_2 = \frac{0.53 \times 2^2}{2} = \frac{0.53 \times 4}{2} = \frac{2.12}{2} = 1.06 \, \text{Å} \] ### Step 3: Calculate the Radius of the First Orbit of Hydrogen For hydrogen (\( \text{H} \)): - \( n = 1 \) (first orbit) - \( Z = 1 \) (atomic number of hydrogen) Substituting these values into the formula: \[ R_1 = \frac{0.53 \times 1^2}{1} = 0.53 \, \text{Å} \] ### Step 4: Compare the Two Radii Now we compare the two calculated radii: - Radius of the second orbit of \( \text{He}^+ \) = \( 1.06 \, \text{Å} \) - Radius of the first orbit of hydrogen = \( 0.53 \, \text{Å} \) Since \( 1.06 \, \text{Å} \neq 0.53 \, \text{Å} \), the assertion is **false**. ### Step 5: Understanding the Reason (R) The reason states that the radius of an orbit in hydrogen-like species is directly proportional to \( n \) and inversely proportional to \( Z \). ### Step 6: Analyze the Proportionality From the formula \( R_n = \frac{0.53 \, n^2}{Z} \): - The radius is **directly proportional to \( n^2 \)**, not \( n \). - The radius is **inversely proportional to \( Z \)**. Thus, the reason is also **false**. ### Conclusion Both the assertion and reason are false. Therefore, the correct option is: **Option D: Both assertion and reason are false.** ---
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