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Correct order of radii...

Correct order of radii

A

`Na gt Mg gt AI`

B

`Na^(+) gt Mg^(2+) gt AI^(3+)`

C

`I+ lt I lt I^(-)`

D

N , He, Ne

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of atomic radii for the given elements, we need to analyze each option based on the periodic trends of atomic size. ### Step-by-Step Solution: **Step 1: Analyze the first option - Sodium (Na), Magnesium (Mg), and Aluminum (Al)** - **Atomic Numbers**: Na = 11, Mg = 12, Al = 13. - **Trend**: As we move from left to right across a period in the periodic table, the atomic radius decreases due to an increase in nuclear charge (more protons) which pulls the electrons closer to the nucleus. - **Conclusion**: The order is Na > Mg > Al. This option is correct. **Step 2: Analyze the second option - Na⁺, Mg²⁺, and Al³⁺** - **Charge and Size**: Na⁺ has lost one electron, Mg²⁺ has lost two, and Al³⁺ has lost three electrons. - **Trend**: As the positive charge increases, the effective nuclear charge increases, leading to a decrease in size. Thus, Na⁺ > Mg²⁺ > Al³⁺. - **Conclusion**: This option is also correct. **Step 3: Analyze the third option - I⁻, I, and I⁺** - **Charge and Size**: I⁻ has gained an electron, I is neutral, and I⁺ has lost an electron. - **Trend**: When an atom gains electrons (anions), it increases in size due to electron-electron repulsion. Conversely, when it loses electrons (cations), the size decreases due to increased nuclear charge. - **Conclusion**: The order is I⁻ > I > I⁺. This option is correct as well. **Step 4: Analyze the fourth option - Nitrogen (N), Helium (He), and Neon (Ne)** - **Atomic Numbers**: N = 7, He = 4, Ne = 10. - **Trend**: Helium has the smallest radius because it has only 1s² electrons. Nitrogen has a larger radius than helium but smaller than neon, which has a full outer shell (1s² 2s² 2p⁶). - **Conclusion**: The correct order is He < N < Ne. This option is incorrect as it states the order incorrectly. ### Final Conclusion: The correct orders of radii are: 1. Na > Mg > Al (correct) 2. Na⁺ > Mg²⁺ > Al³⁺ (correct) 3. I⁻ > I > I⁺ (correct) 4. He < N < Ne (incorrect)
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