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For the given reactions, A rightarrow D,...

For the given reactions, `A rightarrow D, Delta H = x`. Steps involved are
`A rightarrow B, Delta H_(1) = x_(1)`
`B rightarrow C, Delta H_(2) = ?`
`C rightarrow D, Delta H_(3) = x_(3)`

A

`Delta H_(2) = x-(x_(1) + x_(3))`

B

`Delta H_(2) = x + x_(1) + x_(3)`

C

`Delta H_(2) = x_(1) - x_(3) - x`

D

`Delta H_(2) = (x_(1) + x) - x_(3)`

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The correct Answer is:
To solve the problem using Hess's Law, we need to express the enthalpy change for the overall reaction \( A \rightarrow D \) in terms of the enthalpy changes for the individual steps. ### Step-by-Step Solution: 1. **Identify the Overall Reaction and its Enthalpy Change**: - The overall reaction is given as \( A \rightarrow D \) with an enthalpy change \( \Delta H = x \). 2. **Break Down the Overall Reaction into Steps**: - The reaction can be broken down into three steps: - Step 1: \( A \rightarrow B \) with \( \Delta H_{1} = x_{1} \) - Step 2: \( B \rightarrow C \) with \( \Delta H_{2} = ? \) - Step 3: \( C \rightarrow D \) with \( \Delta H_{3} = x_{3} \) 3. **Apply Hess's Law**: - According to Hess's Law, the total enthalpy change for the reaction can be expressed as the sum of the enthalpy changes for each step: \[ \Delta H = \Delta H_{AB} + \Delta H_{BC} + \Delta H_{CD} \] - Substituting the known values: \[ x = x_{1} + \Delta H_{2} + x_{3} \] 4. **Rearranging to Solve for \( \Delta H_{2} \)**: - To find \( \Delta H_{2} \), we rearrange the equation: \[ \Delta H_{2} = x - x_{1} - x_{3} \] 5. **Final Expression**: - Thus, the enthalpy change for the step \( B \rightarrow C \) is: \[ \Delta H_{2} = x - x_{1} - x_{3} \] ### Conclusion: The final answer for \( \Delta H_{2} \) is: \[ \Delta H_{2} = x - x_{1} - x_{3} \]
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