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The temperature of 15 ml of a strong aci...

The temperature of 15 ml of a strong acid increases by `2^(@)C` when 15 ml of a strong base is added to it. If 5 ml of each are mixed, temperature should increase by

A

`0.6^(@)C`

B

`0.3 ^(@)C`

C

`2^(@)C`

D

`6^(@)C`

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The correct Answer is:
To solve the problem, we need to understand the relationship between the volumes of the strong acid and strong base, the heat of neutralization, and the resulting temperature change. ### Step-by-Step Solution: 1. **Understanding the Initial Condition**: - We have 15 ml of a strong acid and 15 ml of a strong base mixed together. - The temperature increase observed when these two are mixed is 2°C. 2. **Heat of Neutralization**: - For strong acids and strong bases, the heat of neutralization is constant. This means that regardless of the volumes mixed, the heat released during the neutralization reaction remains the same. - The heat of neutralization for strong acid and strong base is approximately 57.1 kJ/mol. 3. **Mixing Equal Volumes**: - When we mix equal volumes of a strong acid and a strong base, the temperature change will be the same, regardless of the volume, as long as the volumes are equal. - This is because the heat of neutralization does not change with the volume, and thus the temperature change resulting from the reaction will also remain constant. 4. **Calculating for 5 ml of Each**: - Now, we are mixing 5 ml of the strong acid with 5 ml of the strong base. - Since we are still mixing equal volumes (5 ml of acid and 5 ml of base), the heat of neutralization remains the same as in the previous case. 5. **Conclusion**: - Therefore, the temperature increase when 5 ml of each is mixed will also be the same as when 15 ml of each was mixed, which is 2°C. ### Final Answer: The temperature should increase by **2°C** when 5 ml of each strong acid and strong base are mixed. ---
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