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If x mole of ideal gas at 27^(@)C expand...

If x mole of ideal gas at `27^(@)C` expands isothermally and reversibly from a volume of y to 10 y, then the work done is

A

`w = x R 300 ln y`

B

`w = -300 x R ln y/10y`

C

`w = - 300 x R ln 10`

D

`w = 100 x R ln 1/y`

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The correct Answer is:
To solve the problem of calculating the work done during the isothermal and reversible expansion of an ideal gas, we can follow these steps: ### Step-by-Step Solution: 1. **Identify Given Data:** - Number of moles of gas, \( n = x \) - Initial volume, \( V_1 = y \) - Final volume, \( V_2 = 10y \) - Temperature, \( T = 27^\circ C \) 2. **Convert Temperature to Kelvin:** - To convert Celsius to Kelvin, use the formula: \[ T(K) = T(°C) + 273 \] - Therefore, \[ T = 27 + 273 = 300 \, K \] 3. **Use the Formula for Work Done in Isothermal Expansion:** - The work done during an isothermal reversible expansion is given by the formula: \[ W = -nRT \ln\left(\frac{V_2}{V_1}\right) \] - Here, \( R \) is the universal gas constant. 4. **Substitute the Values into the Formula:** - Substitute \( n = x \), \( R \) (approximately \( 8.314 \, J/(mol \cdot K) \)), \( T = 300 \, K \), \( V_2 = 10y \), and \( V_1 = y \): \[ W = -x \cdot R \cdot 300 \cdot \ln\left(\frac{10y}{y}\right) \] 5. **Simplify the Logarithmic Term:** - Since \( \frac{10y}{y} = 10 \): \[ W = -x \cdot R \cdot 300 \cdot \ln(10) \] 6. **Final Expression for Work Done:** - Thus, the work done \( W \) can be expressed as: \[ W = -300xR \ln(10) \] ### Final Answer: The work done during the isothermal and reversible expansion of the ideal gas is: \[ W = -300xR \ln(10) \]
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