Home
Class 12
CHEMISTRY
The correct thermodynamic conditions for...

The correct thermodynamic conditions for the spontaneous reaction at all temperature is

A

`Delta H lt 0 and Delta S lt 0`

B

`Delta H lt 0 and Delta S = 0`

C

`Delta H gt 0 and Delta S lt 0`

D

`Delta H lt 0 and Delta S gt 0`

Text Solution

Verified by Experts

The correct Answer is:
B, D
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (Section -D) Assertion-Reason Type Questions|15 Videos
  • THERMODYNAMICS

    AAKASH INSTITUTE ENGLISH|Exercise ASSIGNMENT (Section - B) Objective Type Questions|35 Videos
  • THE SOLID STATE

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (SECTION - D) (ASSERTION-REASON TYPE QUESTION)|20 Videos

Similar Questions

Explore conceptually related problems

The correct thermodnamic conditions for the spontaneous reaction at all temperature is:

State the thermodynamic conditions for spontaneous occurrence of a process.

Necessary conditions for spontanity of a reaction ________

In isolated system, find the condition for spontaneous reaction:

The signs of DeltaH,DeltaS and DeltaG for a non-spontaneous reaction at all temperature would e

Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. For the spontaneity of a reaction, which statement is true?

Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. A particular reaction has a negative value for the free energy change. Then at ordinary temperature

For an endothermic reaction to be spontaneous

Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. If an endothermic reaction is non-spontaneous at freezing point of water and becomes feasible at its boiling point, then

Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. Which of the following is true for the reaction? H_(2)O(l) hArr H_(2)O(g) at 100^(@)C and 1 atmosphere

AAKASH INSTITUTE ENGLISH-THERMODYNAMICS-ASSIGNMENT (Section - C) Previous Years Questions
  1. For a given reaction, Delta H = 35.5 kJ mol^(-1) and Delta S = 83.6 JK...

    Text Solution

    |

  2. For a sample of perfect gas when its pressure is changed isothermally ...

    Text Solution

    |

  3. The correct thermodynamic conditions for the spontaneous reaction at a...

    Text Solution

    |

  4. Enthalpy of combustion of carbon to CO2 is -393.5 kJ mol^(-1) Calcu...

    Text Solution

    |

  5. For the reaction: X(2)O(4)(l)rarr2XO(2)(g) DeltaU=2.1kcal , DeltaS...

    Text Solution

    |

  6. In which of the following reactions, standard reaction entropy changes...

    Text Solution

    |

  7. Standard enthalpy of vaporisation Delta("vap")H^(@) for water at 100^(...

    Text Solution

    |

  8. The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy c...

    Text Solution

    |

  9. Equal volumes of two monoatomic gases, A,B at the same temperature and...

    Text Solution

    |

  10. Which of the following is correct option for free expansion of an idea...

    Text Solution

    |

  11. If the enthalpy change for the transition of liquid water to steam is ...

    Text Solution

    |

  12. Enthalpy change for the reaction, 4H(g) to 2H2(g) is -869.6 kJ Th...

    Text Solution

    |

  13. Consider the following processes : {:(,DeltaH(kJ//"mol")),(1/2ArarrB...

    Text Solution

    |

  14. Standard entropies of X(2), Y(2) and XY(3) are 60, 40 and 50 JK^(–1) m...

    Text Solution

    |

  15. Match List I ( Equations) with List II (Type of processes) and select...

    Text Solution

    |

  16. 1 moles of an ideal gas expanded spontaneously into vaccum. The work d...

    Text Solution

    |

  17. For vaporization of water at 1 atmospheric pressure the values of Delt...

    Text Solution

    |

  18. The following teo reaction are known : Fe(2)O(3)(s)+3CO(g)rarr2Fe(s)...

    Text Solution

    |

  19. The values of DeltaH and DeltaS for the reaction, C("graphite")+CO(2...

    Text Solution

    |

  20. From the following bond energies H-H bond energy 431.37 kJ mol^(-1) ...

    Text Solution

    |